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Crystal structures of two C,N-disubstituted acetamides: 2-(4-chlorophenyl)-N-(2-iodophenyl)acetamide and 2-(4-chlorophenyl)-N-(pyrazin-2-yl)acetamide

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dc.contributor.authorNarayana, Badiadka
dc.contributor.authorYathirajan, Hemmige S.
dc.contributor.authorRathore, Ravindranath
dc.contributor.authorGlidewell, Christopher
dc.date.accessioned2016-09-19T11:30:11Z
dc.date.available2016-09-19T11:30:11Z
dc.date.issued2016-09-01
dc.identifier.citationNarayana , B , Yathirajan , H S , Rathore , R & Glidewell , C 2016 , ' Crystal structures of two C,N-disubstituted acetamides: 2-(4-chlorophenyl)- N -(2-iodophenyl)acetamide and 2-(4-chlorophenyl)- N -(pyrazin-2-yl)acetamide ' , Acta Crystallographica Section E: Crystallographic Communications , vol. 72 , no. 9 , pp. 1270-1275 . https://doi.org/10.1107/S2056989016012512en
dc.identifier.issn2056-9890
dc.identifier.otherPURE: 245970979
dc.identifier.otherPURE UUID: b0db7e0a-bb3e-466f-9011-d0ae4935fa22
dc.identifier.otherBibtex: urn:f18c62d72afacbf11a579e31899c6375
dc.identifier.otherScopus: 84999233032
dc.identifier.otherWOS: 000382301000012
dc.identifier.urihttps://hdl.handle.net/10023/9525
dc.descriptionBN thanks the UGC (India) for financial assistance through a BSR one-time grant for the purchase of chemicals.en
dc.description.abstractIn the crystal of 2-(4-chloro­phen­yl)-N-(2-iodo­phen­yl)acetamide, C14H11ClINO, molecules are linked by a combination of N—H⋯O and C—H⋯O hydrogen bonds to form a C(4)C(4)[R21(7)] chain of rings and chains of this type are linked by a combination of C—Cl⋯π(arene) and C—I⋯π(arene) inter­actions to form deeply puckered twofold inter­woven sheets. In the crystal of 2-(4-chloro­phen­yl)-N-(pyrazin-2-yl)acetamide, C12H10ClN3O, mol­ecules are linked into complex sheets by N—H⋯N, C—H⋯N and C—H⋯O hydrogen bonds, and by C—H⋯π(arene) inter­actions.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section E: Crystallographic Communicationsen
dc.rightsThis is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.en
dc.subjectCrystal structureen
dc.subjectC,N-disubstituted acetamidesen
dc.subjectMolecular structureen
dc.subjectMolecular conformationen
dc.subjectHydrogen bondingen
dc.subjectC-halogen...[pi] bonding] bondingen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleCrystal structures of two C,N-disubstituted acetamides: 2-(4-chlorophenyl)-N-(2-iodophenyl)acetamide and 2-(4-chlorophenyl)-N-(pyrazin-2-yl)acetamideen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1107/S2056989016012512
dc.description.statusPeer revieweden


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