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dc.contributor.authorKather, Ralf
dc.contributor.authorRychagova, Elena
dc.contributor.authorCamacho, Paula Sanz
dc.contributor.authorAshbrook, Sharon E.
dc.contributor.authorWoollins, J. Derek
dc.contributor.authorRobben, Lars
dc.contributor.authorLork, Enno
dc.contributor.authorKetkov, Sergey
dc.contributor.authorBeckmann, Jens
dc.identifier.citationKather , R , Rychagova , E , Camacho , P S , Ashbrook , S E , Woollins , J D , Robben , L , Lork , E , Ketkov , S & Beckmann , J 2016 , ' Increasing the Brønsted acidity of Ph 2 PO 2 H by the Lewis acid B(C 6 F 5 ) 3 . Formation of an eight-membered boraphosphinate ring [Ph 2 POB(C 6 F 5 ) 2 O] 2 ' , Chemical Communications , vol. 52 , no. 73 , pp. 10992-10995 .
dc.identifier.otherPURE: 245864533
dc.identifier.otherPURE UUID: 71d05327-47d4-4193-8512-e2185c4aa0f0
dc.identifier.otherScopus: 84984879081
dc.identifier.otherWOS: 000382674000013
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56639000
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779158
dc.descriptionThe Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged for financial support. The theoretical part of this work was supported by the Russian Science Foundation (Project 14-13-00832).en
dc.description.abstractAutoprotolysis of the metastable acid (C6F5)3BOPPh2OH, prepared in situ by the reaction of the rather weak Brønsted acid Ph2PO2H with the strong Lewis acid B(C6F5)3, gave rise to the formation of the eight-membered ring [Ph2POB(C6F5)2O]2 and C6F5H. The conjugate base was isolated as stable sodium crown ether salt [Na(15-crown-5)][Ph2PO2B(C6F5)3].
dc.relation.ispartofChemical Communicationsen
dc.rightsThis is an Open Access article, which is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectElectronic, Optical and Magnetic Materialsen
dc.subjectCeramics and Compositesen
dc.subjectSurfaces, Coatings and Filmsen
dc.subjectMetals and Alloysen
dc.subjectMaterials Chemistryen
dc.titleIncreasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2en
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.description.statusPeer revieweden

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