Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2

Kather, Ralf; Rychagova, Elena; Camacho, Paula Sanz; Ashbrook, Sharon E.; Woollins, J. Derek; Robben, Lars; Lork, Enno; Ketkov, Sergey; Beckmann, Jens

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dc.contributor.author	Kather, Ralf
dc.contributor.author	Rychagova, Elena
dc.contributor.author	Camacho, Paula Sanz
dc.contributor.author	Ashbrook, Sharon E.
dc.contributor.author	Woollins, J. Derek
dc.contributor.author	Robben, Lars
dc.contributor.author	Lork, Enno
dc.contributor.author	Ketkov, Sergey
dc.contributor.author	Beckmann, Jens
dc.date.accessioned	2016-09-15T15:30:14Z
dc.date.available	2016-09-15T15:30:14Z
dc.date.issued	2016-09-21
dc.identifier.citation	Kather , R , Rychagova , E , Camacho , P S , Ashbrook , S E , Woollins , J D , Robben , L , Lork , E , Ketkov , S & Beckmann , J 2016 , ' Increasing the Brønsted acidity of Ph 2 PO 2 H by the Lewis acid B(C 6 F 5 ) 3 . Formation of an eight-membered boraphosphinate ring [Ph 2 POB(C 6 F 5 ) 2 O] 2 ' , Chemical Communications , vol. 52 , no. 73 , pp. 10992-10995 . https://doi.org/10.1039/c6cc06102h	en
dc.identifier.issn	1359-7345
dc.identifier.other	PURE: 245864533
dc.identifier.other	PURE UUID: 71d05327-47d4-4193-8512-e2185c4aa0f0
dc.identifier.other	Scopus: 84984879081
dc.identifier.other	WOS: 000382674000013
dc.identifier.other	ORCID: /0000-0002-4538-6782/work/56639000
dc.identifier.other	ORCID: /0000-0002-1498-9652/work/31779158
dc.identifier.uri	http://hdl.handle.net/10023/9513
dc.description	The Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged for financial support. The theoretical part of this work was supported by the Russian Science Foundation (Project 14-13-00832).	en
dc.description.abstract	Autoprotolysis of the metastable acid (C6F5)3BOPPh2OH, prepared in situ by the reaction of the rather weak Brønsted acid Ph2PO2H with the strong Lewis acid B(C6F5)3, gave rise to the formation of the eight-membered ring [Ph2POB(C6F5)2O]2 and C6F5H. The conjugate base was isolated as stable sodium crown ether salt [Na(15-crown-5)][Ph2PO2B(C6F5)3].
dc.format.extent	4
dc.language.iso	eng
dc.relation.ispartof	Chemical Communications	en
dc.rights	This is an Open Access article, which is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.	en
dc.subject	QD Chemistry	en
dc.subject	Catalysis	en
dc.subject	Electronic, Optical and Magnetic Materials	en
dc.subject	Ceramics and Composites	en
dc.subject	Chemistry(all)	en
dc.subject	Surfaces, Coatings and Films	en
dc.subject	Metals and Alloys	en
dc.subject	Materials Chemistry	en
dc.subject	NDAS	en
dc.subject	BDC	en
dc.subject.lcc	QD	en
dc.title	Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2	en
dc.type	Journal article	en
dc.description.version	Publisher PDF	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.contributor.institution	University of St Andrews. Office of the Principal	en
dc.identifier.doi	https://doi.org/10.1039/c6cc06102h
dc.description.status	Peer reviewed	en

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