Show simple item record

Files in this item

Thumbnail
Name:
Beckmann_2016_ChemComms_BronstedAcidity_CC.pdf
Size:
1.994Mb
Format:
PDF
View/Open

Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2

Item metadata

dc.contributor.authorKather, Ralf
dc.contributor.authorRychagova, Elena
dc.contributor.authorCamacho, Paula Sanz
dc.contributor.authorAshbrook, Sharon E.
dc.contributor.authorWoollins, J. Derek
dc.contributor.authorRobben, Lars
dc.contributor.authorLork, Enno
dc.contributor.authorKetkov, Sergey
dc.contributor.authorBeckmann, Jens
dc.date.accessioned2016-09-15T15:30:14Z
dc.date.available2016-09-15T15:30:14Z
dc.date.issued2016-09-21
dc.identifier245864533
dc.identifier71d05327-47d4-4193-8512-e2185c4aa0f0
dc.identifier84984879081
dc.identifier000382674000013
dc.identifier.citationKather , R , Rychagova , E , Camacho , P S , Ashbrook , S E , Woollins , J D , Robben , L , Lork , E , Ketkov , S & Beckmann , J 2016 , ' Increasing the Brønsted acidity of Ph 2 PO 2 H by the Lewis acid B(C 6 F 5 ) 3 . Formation of an eight-membered boraphosphinate ring [Ph 2 POB(C 6 F 5 ) 2 O] 2 ' , Chemical Communications , vol. 52 , no. 73 , pp. 10992-10995 . https://doi.org/10.1039/c6cc06102hen
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56639000
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779158
dc.identifier.urihttps://hdl.handle.net/10023/9513
dc.descriptionThe Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged for financial support. The theoretical part of this work was supported by the Russian Science Foundation (Project 14-13-00832).en
dc.description.abstractAutoprotolysis of the metastable acid (C6F5)3BOPPh2OH, prepared in situ by the reaction of the rather weak Brønsted acid Ph2PO2H with the strong Lewis acid B(C6F5)3, gave rise to the formation of the eight-membered ring [Ph2POB(C6F5)2O]2 and C6F5H. The conjugate base was isolated as stable sodium crown ether salt [Na(15-crown-5)][Ph2PO2B(C6F5)3].
dc.format.extent4
dc.format.extent2091266
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectQD Chemistryen
dc.subjectCatalysisen
dc.subjectElectronic, Optical and Magnetic Materialsen
dc.subjectCeramics and Compositesen
dc.subjectChemistry(all)en
dc.subjectSurfaces, Coatings and Filmsen
dc.subjectMetals and Alloysen
dc.subjectMaterials Chemistryen
dc.subjectNDASen
dc.subjectBDCen
dc.subject.lccQDen
dc.titleIncreasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1039/c6cc06102h
dc.description.statusPeer revieweden


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.