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Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands
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dc.contributor.author | Chalmers, Brian Alexander | |
dc.contributor.author | Buehl, Michael | |
dc.contributor.author | Nejman, Phillip | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.contributor.author | Kilian, Petr | |
dc.date.accessioned | 2016-09-08T23:33:59Z | |
dc.date.available | 2016-09-08T23:33:59Z | |
dc.date.issued | 2015 | |
dc.identifier | 215234127 | |
dc.identifier | b62347ec-ddc5-43f2-9f49-27c32bd38a2d | |
dc.identifier | 84942105117 | |
dc.identifier | 000366589600010 | |
dc.identifier.citation | Chalmers , B A , Buehl , M , Nejman , P , Slawin , A M Z , Woollins , J D & Kilian , P 2015 , ' Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands ' , Journal of Organometallic Chemistry , vol. In press . https://doi.org/10.1016/j.jorganchem.2015.09.006 | en |
dc.identifier.issn | 0022-328X | |
dc.identifier.other | ORCID: /0000-0002-1095-7143/work/48131814 | |
dc.identifier.other | ORCID: /0000-0002-2999-2272/work/55901234 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861934 | |
dc.identifier.other | ORCID: /0000-0001-6379-3026/work/58285417 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779172 | |
dc.identifier.uri | https://hdl.handle.net/10023/9462 | |
dc.description | This work was financially supported by the EPSRC and the EPSRC National Mass Spectrometry Service Centre (NMSSC) Swansea. | en |
dc.description.abstract | The syntheses of rhodium(III) and iridium(III) half sandwich complexes containing tertiary arsine and stibine ligands of the form [Cp*M(L)Cl2] (M = Rh, Ir; L = AsEt3, AsPh3, SbPh3) are reported. These compounds represent infrequent examples of rhodium and iridium metal complexes bearing arsenic or antimony ligands. All new compounds were fully characterised using 1H and 13C NMR spectroscopy, mass spectrometry and single crystal X-ray diffraction. DFT calculations show the formation of the complexes from (Cp*MCl2)2 and EPh3 (E = P, As, Sb) to be highly exothermic, although the enthalpic driving force is decreasing in the expected sequence P > As > Sb. | |
dc.format.extent | 1888577 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Organometallic Chemistry | en |
dc.subject | Arsine | en |
dc.subject | Stibine | en |
dc.subject | Rhodium | en |
dc.subject | Iridium | en |
dc.subject | Half-sandwich complex | en |
dc.subject | DFT calculations | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1016/j.jorganchem.2015.09.006 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-09-08 | |
dc.identifier.url | http://www.sciencedirect.com/science/article/pii/S0022328X15301352#appd001 | en |
dc.identifier.grantnumber | EP/K503940/1 | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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