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dc.contributor.authorChalmers, Brian Alexander
dc.contributor.authorBuehl, Michael
dc.contributor.authorNejman, Phillip
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorKilian, Petr
dc.date.accessioned2016-09-08T23:33:59Z
dc.date.available2016-09-08T23:33:59Z
dc.date.issued2015
dc.identifier.citationChalmers , B A , Buehl , M , Nejman , P , Slawin , A M Z , Woollins , J D & Kilian , P 2015 , ' Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands ' Journal of Organometallic Chemistry , vol. In press . https://doi.org/10.1016/j.jorganchem.2015.09.006en
dc.identifier.issn0022-328X
dc.identifier.otherPURE: 215234127
dc.identifier.otherPURE UUID: b62347ec-ddc5-43f2-9f49-27c32bd38a2d
dc.identifier.otherScopus: 84942105117
dc.identifier.otherORCID: /0000-0002-1095-7143/work/48131814
dc.identifier.otherORCID: /0000-0002-2999-2272/work/55901234
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/S0022328X15301352#appd001en
dc.descriptionThis work was financially supported by the EPSRC and the EPSRC National Mass Spectrometry Service Centre (NMSSC) Swansea.en
dc.description.abstractThe syntheses of rhodium(III) and iridium(III) half sandwich complexes containing tertiary arsine and stibine ligands of the form [Cp*M(L)Cl2] (M = Rh, Ir; L = AsEt3, AsPh3, SbPh3) are reported. These compounds represent infrequent examples of rhodium and iridium metal complexes bearing arsenic or antimony ligands. All new compounds were fully characterised using 1H and 13C NMR spectroscopy, mass spectrometry and single crystal X-ray diffraction. DFT calculations show the formation of the complexes from (Cp*MCl2)2 and EPh3 (E = P, As, Sb) to be highly exothermic, although the enthalpic driving force is decreasing in the expected sequence P > As > Sb.
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.rightsCopyright © 2015 Published by Elsevier B.V. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1016/j.jorganchem.2015.09.006en
dc.subjectArsineen
dc.subjectStibineen
dc.subjectRhodiumen
dc.subjectIridiumen
dc.subjectHalf-sandwich complexen
dc.subjectDFT calculationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleRhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.identifier.doihttps://doi.org/10.1016/j.jorganchem.2015.09.006
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-09-08


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