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dc.contributor.authorChalmers, Brian Alexander
dc.contributor.authorBuehl, Michael
dc.contributor.authorNejman, Phillip
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorKilian, Petr
dc.date.accessioned2016-09-08T23:33:59Z
dc.date.available2016-09-08T23:33:59Z
dc.date.issued2015
dc.identifier215234127
dc.identifierb62347ec-ddc5-43f2-9f49-27c32bd38a2d
dc.identifier84942105117
dc.identifier000366589600010
dc.identifier.citationChalmers , B A , Buehl , M , Nejman , P , Slawin , A M Z , Woollins , J D & Kilian , P 2015 , ' Rhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligands ' , Journal of Organometallic Chemistry , vol. In press . https://doi.org/10.1016/j.jorganchem.2015.09.006en
dc.identifier.issn0022-328X
dc.identifier.otherORCID: /0000-0002-1095-7143/work/48131814
dc.identifier.otherORCID: /0000-0002-2999-2272/work/55901234
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861934
dc.identifier.otherORCID: /0000-0001-6379-3026/work/58285417
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779172
dc.identifier.urihttps://hdl.handle.net/10023/9462
dc.descriptionThis work was financially supported by the EPSRC and the EPSRC National Mass Spectrometry Service Centre (NMSSC) Swansea.en
dc.description.abstractThe syntheses of rhodium(III) and iridium(III) half sandwich complexes containing tertiary arsine and stibine ligands of the form [Cp*M(L)Cl2] (M = Rh, Ir; L = AsEt3, AsPh3, SbPh3) are reported. These compounds represent infrequent examples of rhodium and iridium metal complexes bearing arsenic or antimony ligands. All new compounds were fully characterised using 1H and 13C NMR spectroscopy, mass spectrometry and single crystal X-ray diffraction. DFT calculations show the formation of the complexes from (Cp*MCl2)2 and EPh3 (E = P, As, Sb) to be highly exothermic, although the enthalpic driving force is decreasing in the expected sequence P > As > Sb.
dc.format.extent1888577
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.subjectArsineen
dc.subjectStibineen
dc.subjectRhodiumen
dc.subjectIridiumen
dc.subjectHalf-sandwich complexen
dc.subjectDFT calculationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleRhodium(III) and iridium(III) half-sandwich complexes with tertiary arsine and stibine ligandsen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1016/j.jorganchem.2015.09.006
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-09-08
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X15301352#appd001en
dc.identifier.grantnumberEP/K503940/1en
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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