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dc.contributor.authorCharkin , Dmitri O.
dc.contributor.authorBlack, Cameron
dc.contributor.authorDownie, Lewis James
dc.contributor.authorSklovsky, Dmitry E.
dc.contributor.authorBerdonosov, Peter S.
dc.contributor.authorOlenev , Andrei V.
dc.contributor.authorZhou, Wuzong
dc.contributor.authorLightfoot, Philip
dc.contributor.authorDolgikh, Valery A.
dc.identifier.citationCharkin , D O , Black , C , Downie , L J , Sklovsky , D E , Berdonosov , P S , Olenev , A V , Zhou , W , Lightfoot , P & Dolgikh , V A 2015 , ' Cs 7 Sm 11 [TeO 3 ] 12 Cl 16 and Rb 7 Nd 11 [TeO 3 ] 12 Br 16 , the new tellurite halides of the tetragonal Rb 6 LiNd 11 [SeO 3 ] 12 Cl 16 structure type ' , Journal of Solid State Chemistry , vol. 232 , pp. 56-61 .
dc.identifier.otherRIS: urn:9F4FA7D7B511FC5C2913140FF3EB059F
dc.identifier.otherORCID: /0000-0001-9752-7076/work/58055038
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464461
dc.descriptionThe authors thank the Russian Foundation for Basic Researches for the support of this work under Grants No. 14-03-00604_a and 12-03-92604-KO_a. The X-ray study of compound II was made possible due to M.V. Lomonosov Moscow State University Programm of Development. PL thanks the University of St Andrews and EPSRC for DTA Studentships to CB and LJD.en
dc.description.abstractTwo new rare-earth – alkali – tellurium oxide halides were synthesized by a salt flux technique and characterized by single-crystal X-ray diffraction. The structures of the new compounds Cs7Sm11[TeO3]12Cl16 (I) and Rb7Nd11[TeO3]12Br16 (II) (both tetragonal, space group I4/mcm) correspond to the sequence of [MLn11(TeO3)12] and [M6×16] layers and bear very strong similarities to those of known selenite analogs. We discuss the trends in similarities and differences in compositions and structural details between the Se and Te compounds; more members of the family are predicted.
dc.relation.ispartofJournal of Solid State Chemistryen
dc.subjectStructure elucidationen
dc.subjectCrystal engineeringen
dc.subjectLayered compoundsen
dc.subjectQD Chemistryen
dc.titleCs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure typeen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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