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Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

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dc.contributor.authorCharkin , Dmitri O.
dc.contributor.authorBlack, Cameron
dc.contributor.authorDownie, Lewis James
dc.contributor.authorSklovsky, Dmitry E.
dc.contributor.authorBerdonosov, Peter S.
dc.contributor.authorOlenev , Andrei V.
dc.contributor.authorZhou, Wuzong
dc.contributor.authorLightfoot, Philip
dc.contributor.authorDolgikh, Valery A.
dc.date.accessioned2016-08-30T23:32:42Z
dc.date.available2016-08-30T23:32:42Z
dc.date.issued2015-12
dc.identifier.citationCharkin , D O , Black , C , Downie , L J , Sklovsky , D E , Berdonosov , P S , Olenev , A V , Zhou , W , Lightfoot , P & Dolgikh , V A 2015 , ' Cs 7 Sm 11 [TeO 3 ] 12 Cl 16 and Rb 7 Nd 11 [TeO 3 ] 12 Br 16 , the new tellurite halides of the tetragonal Rb 6 LiNd 11 [SeO 3 ] 12 Cl 16 structure type ' , Journal of Solid State Chemistry , vol. 232 , pp. 56-61 . https://doi.org/10.1016/j.jssc.2015.08.043en
dc.identifier.issn0022-4596
dc.identifier.otherPURE: 213551865
dc.identifier.otherPURE UUID: 2d635361-c376-4fb8-a411-fe68d79a731a
dc.identifier.otherRIS: urn:9F4FA7D7B511FC5C2913140FF3EB059F
dc.identifier.otherScopus: 84941132053
dc.identifier.otherORCID: /0000-0001-9752-7076/work/58055038
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464461
dc.identifier.otherWOS: 000364265500010
dc.identifier.urihttps://hdl.handle.net/10023/9402
dc.descriptionThe authors thank the Russian Foundation for Basic Researches for the support of this work under Grants No. 14-03-00604_a and 12-03-92604-KO_a. The X-ray study of compound II was made possible due to M.V. Lomonosov Moscow State University Programm of Development. PL thanks the University of St Andrews and EPSRC for DTA Studentships to CB and LJD.en
dc.description.abstractTwo new rare-earth – alkali – tellurium oxide halides were synthesized by a salt flux technique and characterized by single-crystal X-ray diffraction. The structures of the new compounds Cs7Sm11[TeO3]12Cl16 (I) and Rb7Nd11[TeO3]12Br16 (II) (both tetragonal, space group I4/mcm) correspond to the sequence of [MLn11(TeO3)12] and [M6×16] layers and bear very strong similarities to those of known selenite analogs. We discuss the trends in similarities and differences in compositions and structural details between the Se and Te compounds; more members of the family are predicted.
dc.language.isoeng
dc.relation.ispartofJournal of Solid State Chemistryen
dc.rightsCopyright © 2015 Published by Elsevier Inc. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1016/j.jssc.2015.08.043en
dc.subjectLanthanidesen
dc.subjectTelluriumen
dc.subjectStructure elucidationen
dc.subjectCrystal engineeringen
dc.subjectLayered compoundsen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleCs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure typeen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.jssc.2015.08.043
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-08-30
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022459615301456#appd001en


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