Solid-phase synthesis and catalytic screening of polystyrene supported diphosphines
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An efficient modular method towards the synthesis of a library of polystyrene supported diphosphine ligands by combining solid-phase synthesis with rational ligand design has been developed. These supported ligands, obtained in quantitative yield, were efficiently and effectively screened in Rh-catalysed asymmetric hydrogenation of several benchmark substrates.
Samuels , M C , Heutz , F J L , Grabulosa , A & Kamer , P C J 2016 , ' Solid-phase synthesis and catalytic screening of polystyrene supported diphosphines ' Topics In Catalysis , vol 59 , no. 19 , pp. 1793-1799 . DOI: 10.1007/s11244-016-0700-1
Topics In Catalysis
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DescriptionThe authors thank the European Union (Marie Curie ITN SusPhos, grant agreement no. 317404) for financial support.
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