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dc.contributor.authorHow, Rebecca Catherine
dc.contributor.authorHembre, Robert
dc.contributor.authorPonasik, James A.
dc.contributor.authorTolleson, Ginette S.
dc.contributor.authorClarke, Matt
dc.date.accessioned2016-07-27T23:31:08Z
dc.date.available2016-07-27T23:31:08Z
dc.date.issued2016-01-07
dc.identifier.citationHow , R C , Hembre , R , Ponasik , J A , Tolleson , G S & Clarke , M 2016 , ' A modular family of phosphine-phosphoramidite ligands and their hydroformylation catalysts : steric tuning impacts upon the coordination geometry of trigonal bipyramidal complexes of type [Rh(H)(CO) 2 (P^P*)] ' , Catalysis Science & Technology , vol. 6 , pp. 118-124 . https://doi.org/10.1039/C5CY00886Gen
dc.identifier.issn2044-4753
dc.identifier.otherPURE: 231867854
dc.identifier.otherPURE UUID: 8fb7f961-ccc8-41c9-8e92-c8512774b708
dc.identifier.otherBibtex: urn:1c1c6343978a4122059f5a7ac919f4c9
dc.identifier.otherScopus: 84951777739
dc.identifier.otherORCID: /0000-0002-2444-1244/work/59464615
dc.identifier.otherWOS: 000366857300009
dc.identifier.urihttp://hdl.handle.net/10023/9219
dc.descriptionThe authors thank the Eastman Chemical Company for funding.en
dc.description.abstractFour new phosphine-phosphoramidite bidentate ligands have been synthesised and studied in rhodium-catalysed hydroformylation. Variable temperature NMR studies have been used along with HPIR to investigate the coordination mode of the trigonal bipyramidal complexes formed from [Rh(acac)(CO)2], ligand and syngas. It was found that small changes to the ligand structure have a large effect on the geometry of the active catalytic species. The rhodium catalysts of these new ligands were found to give unusually high iso-selectivity in the hydroformylation of propene and 1-octene.
dc.format.extent7
dc.language.isoeng
dc.relation.ispartofCatalysis Science & Technologyen
dc.rightsCopyright 2015 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1039/C5CY00886Gen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleA modular family of phosphine-phosphoramidite ligands and their hydroformylation catalysts : steric tuning impacts upon the coordination geometry of trigonal bipyramidal complexes of type [Rh(H)(CO)2(P^P*)]en
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5CY00886G
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-07-28
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/cy/c5cy00886g/c5cy00886g1.pdfen


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