Raman scattering with strongly coupled vibron-polaritons
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Strong coupling between cavity photons and molecular vibrations can lead to the formation of vibron-polaritons. In a recent experiment with PVAc molecules in a metal-metal microcavity [A.Shalabney et al., Ang.Chem.Int.Ed. 54 7971 (2015)], such a coupling was observed to enhance the Raman scattering probability by several orders of magnitude. Inspired by this, we theoretically analyze the effect of strong photon-vibron coupling on the Raman scattering amplitude of organic molecules. This problem has recently been addressed in [J.del Pino, J.Feist and F.J.Garcia-Vidal; J.Phys.Chem.C 119 29132 (2015)] using exact numerics for a small number of molecules. In this paper we derive compact analytic results for any number of molecules, also including the ultra-strong coupling regime. Our calculations predict a division of the Raman signal into upper and lower polariton modes,with some enhancement to the lower polariton Raman amplitude due to the mode softening under strong coupling.
Strashko , A & Keeling , J 2016 , ' Raman scattering with strongly coupled vibron-polaritons ' , Physical Review. A, Atomic, molecular, and optical physics , vol. 94 , no. 2 , 023843 . https://doi.org/10.1103/PhysRevA.94.023843
Physical Review. A, Atomic, molecular, and optical physics
© 2016, American Physical Society. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at journals.aps.org / http://dx.doi.org/10.1103/PhysRevA.94.023843
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