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dc.contributor.authorBantreil, Xavier
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2016-05-19T23:32:30Z
dc.date.available2016-05-19T23:32:30Z
dc.date.issued2015-07
dc.identifier188747402
dc.identifier7c82d32b-23db-4751-876c-a4d411c5d49b
dc.identifier84930865307
dc.identifier000356040600004
dc.identifier.citationBantreil , X & Cazin , C S J 2015 , ' Phosphite ligands in Ru-based olefin metathesis catalysts ' , Monatshefte für Chemie , vol. 146 , no. 7 , pp. 1043-1052 . https://doi.org/10.1007/s00706-015-1487-7en
dc.identifier.issn0026-9247
dc.identifier.urihttps://hdl.handle.net/10023/8839
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC), the CNRS (Centre National de la Recherche Scientifique) and l'Université de Montpellier for funding.en
dc.description.abstractIn this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong σ-donating NHC ligands and π-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis and ring-opening metathesis polymerization is presented as well as DFT calculations describing our mechanistic understanding.
dc.format.extent992044
dc.language.isoeng
dc.relation.ispartofMonatshefte für Chemieen
dc.subjectPhosphiteen
dc.subjectMetal complexesen
dc.subjectMetathesisen
dc.subjectCoordinationen
dc.subjectChemistryen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titlePhosphite ligands in Ru-based olefin metathesis catalystsen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1007/s00706-015-1487-7
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-05-20
dc.identifier.grantnumberUF100691en


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