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dc.contributor.authorPal, Amlan Kumar
dc.contributor.authorCordes, David Bradford
dc.contributor.authorPringouri, Konstantina
dc.contributor.authorAnwar, Muhammad
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorRawson, Jeremy
dc.contributor.authorZysman-Colman, Eli
dc.date.accessioned2016-05-05T14:32:45Z
dc.date.available2016-05-05T14:32:45Z
dc.date.issued2016
dc.identifier.citationPal , A K , Cordes , D B , Pringouri , K , Anwar , M , Slawin , A M Z , Rawson , J & Zysman-Colman , E 2016 , ' Synthesis and characterization of green-to-yellow emissive Ir(III) complexes of pyridylbenzothiadiazine ligand ' , Journal of Coordination Chemistry , vol. 69 , no. 11-13 , pp. 1924-1937 . https://doi.org/10.1080/00958972.2016.1170818en
dc.identifier.issn0095-8972
dc.identifier.otherPURE: 241426219
dc.identifier.otherPURE UUID: 33a4db29-5fcd-4dde-a403-265b1eb076c3
dc.identifier.otherScopus: 84963815529
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023983
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639075
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861605
dc.identifier.otherORCID: /0000-0002-5677-5070/work/59464922
dc.identifier.otherWOS: 000380129800025
dc.identifier.urihttp://hdl.handle.net/10023/8726
dc.descriptionEZ-C acknowledges the University of St Andrews for financial support. The authors are grateful to the EPSRC for financial support from grant EP/M02105X/1. JMR would like to thank NSERC Canada, the Canada Research Chair Program and CFI/ORF for financial support. KP acknowledges financial support through the Ontario Trillium Scholarship program.en
dc.description.abstractReaction of Tetrakis(2-phenylpyridinato-C2,N')(μ-dichloro)di-iridium with 3-(pyridin-2-yl)-4H-benzo[e][1,2,4]thiadiazine ( L1 ) under neutral and basic media afforded the charged and neutral Ir-complexes, 1 and 2 , respectively, in good yields (63 – 79%). Single crystal XRD analysis confirms that the ancillary ligands in both 1 and 2 binds to the iridium via coordination of N2 of the benzo[e][1,2,4]thiadiazine. Upon isolation of the neutral complex, the sulfur atom rapidly oxidizes to form 2 . The UV-vis absorption spectra of the complexes exhibit both ligand-centered and mixed metal-to-ligand and ligand-to-ligand charged transfer (CT) transitions that are typical of many heteroleptic iridium complexes. Complexes 1 and 2 were found to be emissive at room temperature in the green and yellow region of the electromagnetic spectrum, respectively, albeit with poor photoluminescence quantum yield (ΦPL = 1.1 – 2.5%).
dc.format.extent14
dc.language.isoeng
dc.relation.ispartofJournal of Coordination Chemistryen
dc.rights© 2016 The Author(s). Published by Taylor & Francis This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Permission is granted subject to the terms of the License under which the work was published. Please check the License conditions for the work which you wish to reuse. Full and appropriate attribution must be given. This permission does not cover any third party copyrighted material which may appear in the work requested.en
dc.subjectIr-complexen
dc.subjectBenzothiadiazine liganden
dc.subjectDFT studiesen
dc.subjectXRD analysisen
dc.subjectPhotophysicsen
dc.subjectElectrochemistryen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSynthesis and characterization of green-to-yellow emissive Ir(III) complexes of pyridylbenzothiadiazine liganden
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Organic Semiconductor Centreen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1080/00958972.2016.1170818
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/M02105X/1en


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