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dc.contributor.authorDehaney-Steven, Zachary Alexander
dc.contributor.authorPapargyriou, Despoina
dc.contributor.authorIrvine, John Thomas Sirr
dc.date.accessioned2016-05-03T11:30:08Z
dc.date.available2016-05-03T11:30:08Z
dc.date.issued2016-05
dc.identifier240305497
dc.identifierf53aa3d2-6b25-4e31-8a13-7b2ab449603c
dc.identifier84955618942
dc.identifier000376710900065
dc.identifier.citationDehaney-Steven , Z A , Papargyriou , D & Irvine , J T S 2016 , ' Flux investigations on composite (La 0.8 Sr 0.2 ) 0.95 Cr 0.5 Fe 0.5 O 3 − δ –Sc 0.198 Ce 0.012 Zr 0.789 O 1.90 oxygen transport membranes ' , Solid State Ionics , vol. 288 , pp. 338-341 . https://doi.org/10.1016/j.ssi.2016.01.017en
dc.identifier.issn0167-2738
dc.identifier.otherORCID: /0000-0002-8394-3359/work/68280807
dc.identifier.urihttps://hdl.handle.net/10023/8714
dc.descriptionThe authors would like to thank Praxair for funding and Jonathan Lane for helpful discussions, we also acknowledge support from EPSRC for Platform Grant EP/K015540/1and the Royal Society for Wolfson Merit Award WRMA 2012/R2.en
dc.description.abstractOxygen permeation measurements were performed on planar membranes of (La0.8Sr0.2)0.95Cr0.5Fe0.5O3 − δ (LSCrF)–Sc0.198Ce0.012Zr0.789O1.90 (10Sc1CeSZ) with various exchange layers and membrane thicknesses. Addition of a fuel side exchange layer capable of nickel exsolution provided approximately twice the performance compared with no exsolved catalyst for a 300 μm thick membrane at 900 °C. Use of a 20 μm thick membrane with a porous support structure produced a further 7 fold improvement in oxygen flux at 900 °C to yield 3.54 ml cm− 2 min− 1.
dc.format.extent4
dc.format.extent512197
dc.language.isoeng
dc.relation.ispartofSolid State Ionicsen
dc.subjectOyxgen transport membraneen
dc.subjectPerovskiteen
dc.subjectFluoriteen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleFlux investigations on composite (La0.8Sr0.2)0.95Cr0.5Fe0.5O3 − δ–Sc0.198Ce0.012Zr0.789O1.90 oxygen transport membranesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.ssi.2016.01.017
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/K015540/1en
dc.identifier.grantnumberWRMA 2012/R2en
dc.identifier.grantnumberEP/J018139/1en


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