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dc.contributor.authorZysman-Colman, Eli
dc.contributor.authorGhosh, Sanjay Sanatan
dc.contributor.authorXie, Guohua
dc.contributor.authorVarghese, Shinto
dc.contributor.authorChowdhury, Mithun
dc.contributor.authorSharma, Nidhi
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorSamuel, Ifor David William
dc.date.accessioned2016-04-26T11:30:04Z
dc.date.available2016-04-26T11:30:04Z
dc.date.issued2016-04-13
dc.identifier241577673
dc.identifier84517938-679f-4838-b3a0-d4be370a2a0f
dc.identifier84964837331
dc.identifier000374274900047
dc.identifier.citationZysman-Colman , E , Ghosh , S S , Xie , G , Varghese , S , Chowdhury , M , Sharma , N , Cordes , D B , Slawin , A M Z & Samuel , I D W 2016 , ' Solution-processable silicon phthalocyanines in electroluminescent and photovoltaic devices ' , ACS Applied Materials & Interfaces , vol. 8 , no. 14 , pp. 9247−9253 . https://doi.org/10.1021/acsami.5b12408en
dc.identifier.issn1944-8252
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28023984
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639076
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861606
dc.identifier.urihttps://hdl.handle.net/10023/8679
dc.descriptionE.Z.-C. acknowledges the University of St. Andrews for financial support. The authors thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. I.D.W.S. acknowledges support from the EPSRC (grant EP/J01771X), the European Research Council (grant 321305), and a Royal Society Wolfson Research Merit Award.en
dc.description.abstractPhthalocyanines and their main group and metal complexes are important classes of organic semiconductor materials, but are usually highly insoluble so frequently need to be processed by vacuum deposition in devices. We report two highly soluble silicon phthalocyanine (SiPc) diester compounds and demonstrate their potential as organic semiconductor materials. Near-infrared (λEL = 698-709 nm) solution-processed organic light- emitting diodes (OLEDs) were fabricated and exhibited external quantum efficiencies (EQEs) of up to 1.4%. Binary bulk heterojunction solar cells employing P3HT or PTB7 as the donor and the SiPc as the acceptor provided power conversion efficiencies (PCE) of up to 2.7% under simulated solar illumination. Our results show that soluble SiPcs are promising materials for organic electronics.
dc.format.extent2917986
dc.language.isoeng
dc.relation.ispartofACS Applied Materials & Interfacesen
dc.subjectSilicon phthalocyaninesen
dc.subjectSingle crystalsen
dc.subjectNear-IR emissionen
dc.subjectSolution-processable organic light-emitting diodesen
dc.subjectOrganic solar cellsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectSDG 7 - Affordable and Clean Energyen
dc.subject.lccQDen
dc.titleSolution-processable silicon phthalocyanines in electroluminescent and photovoltaic devicesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Physics and Astronomyen
dc.contributor.institutionUniversity of St Andrews. Condensed Matter Physicsen
dc.identifier.doi10.1021/acsami.5b12408
dc.description.statusPeer revieweden
dc.identifier.urlhttp://pubs.acs.org/doi/suppl/10.1021/acsami.5b12408en
dc.identifier.grantnumberEP/J01771X/1en
dc.identifier.grantnumberen


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