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Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates : application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenes

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dc.contributor.authorIakobson, George
dc.contributor.authorDu, Junyi
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorBeier, Petr
dc.date.accessioned2016-04-22T08:37:40Z
dc.date.available2016-04-22T08:37:40Z
dc.date.issued2015-08-26
dc.identifier242077307
dc.identifier9256e7e8-2631-42cf-a99b-3770ac53cebf
dc.identifier84962130140
dc.identifier000360037400001
dc.identifier.citationIakobson , G , Du , J , Slawin , A M Z & Beier , P 2015 , ' Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates : application to the synthesis of SF 5 -substituted phenylboronic esters and iodobenzenes ' , Beilstein Journal of Organic Chemistry , vol. 11 , pp. 1494-1502 . https://doi.org/10.3762/bjoc.11.162en
dc.identifier.issn1860-5397
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861897
dc.identifier.urihttps://hdl.handle.net/10023/8667
dc.descriptionFinancial support from the Academy of Sciences of the Czech Republic (Research Plan RVO: 61388963) and the Grant Agency of the Czech Republic (P207/12/0072) is gratefully acknowledged.en
dc.description.abstractPyridine promotes dediazoniation of aryldiazonium tetrafluoroborates. The formed aryl radicals were trapped with B2pin2, iodine, or tetrahydrofuran to afford boronic esters, iodobenzenes and benzenes, respectively. The application to the synthesis of (pentafluorosulfanyl) phenylboronic esters, iodo(pentafluorosulfanyl)benzenes and (pentafluorosulfanyl)benzene is shown.
dc.format.extent9
dc.format.extent374608
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.subjectBorylationen
dc.subjectDiazonium saltsen
dc.subjectIodinationen
dc.subjectPyridineen
dc.subjectSulfur pentafluoridesen
dc.subjectQD Chemistryen
dc.subjectOrganic Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titlePyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates : application to the synthesis of SF5-substituted phenylboronic esters and iodobenzenesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.3762/bjoc.11.162
dc.description.statusPeer revieweden


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