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dc.contributor.authorThalangamaarachchige, Vidura D.
dc.contributor.authorUnruh, Daniel K.
dc.contributor.authorCordes, David Bradford
dc.contributor.authorKrempner, Clemens
dc.identifier.citationThalangamaarachchige , V D , Unruh , D K , Cordes , D B & Krempner , C 2015 , ' Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides ' , Inorganic Chemistry , vol. 54 , no. 9 , pp. 4189-4191 .
dc.identifier.otherPURE: 187416375
dc.identifier.otherPURE UUID: 82f864d1-47d8-43d3-ae42-7e0605ea8e23
dc.identifier.otherScopus: 84929224108
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024004
dc.identifier.otherWOS: 000354075600005
dc.description.abstractThe synthesis and structures of the first zwitterionic divalent rare-earth metal silanides of the formula [Si(SiMe2OMe)3-κ3]2M (M-3), where M = Eu, Yb, and Sm, are reported. M-3 compounds feature spirocyclic bicyclooctane structures in which the central rare-earth metal ions are being octahedrally coordinated by six methoxy groups. The reaction of Yb-3 with BPh3 and W(CO)6 respectively generated the trinuclear zwitterions [Ph3BSi(SiMe2OMe)3-κ3]2Yb (Yb-4) and [(CO)5WSi(SiMe2OMe)3-κ3]2Yb (Yb-5) in good yield.
dc.relation.ispartofInorganic Chemistryen
dc.rightsCopyright © 2015 American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see
dc.subjectQD Chemistryen
dc.titleSynthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanidesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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