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Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides
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| dc.contributor.author | Thalangamaarachchige, Vidura D. | |
| dc.contributor.author | Unruh, Daniel K. | |
| dc.contributor.author | Cordes, David Bradford | |
| dc.contributor.author | Krempner, Clemens | |
| dc.date.accessioned | 2016-04-22T08:37:20Z | |
| dc.date.available | 2016-04-22T08:37:20Z | |
| dc.date.issued | 2015-05-04 | |
| dc.identifier | 187416375 | |
| dc.identifier | 82f864d1-47d8-43d3-ae42-7e0605ea8e23 | |
| dc.identifier | 84929224108 | |
| dc.identifier | 000354075600005 | |
| dc.identifier.citation | Thalangamaarachchige , V D , Unruh , D K , Cordes , D B & Krempner , C 2015 , ' Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides ' , Inorganic Chemistry , vol. 54 , no. 9 , pp. 4189-4191 . https://doi.org/10.1021/acs.inorgchem.5b00542 | en |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28024004 | |
| dc.identifier.uri | https://hdl.handle.net/10023/8663 | |
| dc.description.abstract | The synthesis and structures of the first zwitterionic divalent rare-earth metal silanides of the formula [Si(SiMe2OMe)3-κ3]2M (M-3), where M = Eu, Yb, and Sm, are reported. M-3 compounds feature spirocyclic bicyclooctane structures in which the central rare-earth metal ions are being octahedrally coordinated by six methoxy groups. The reaction of Yb-3 with BPh3 and W(CO)6 respectively generated the trinuclear zwitterions [Ph3BSi(SiMe2OMe)3-κ3]2Yb (Yb-4) and [(CO)5WSi(SiMe2OMe)3-κ3]2Yb (Yb-5) in good yield. | |
| dc.format.extent | 450255 | |
| dc.language.iso | eng | |
| dc.relation.ispartof | Inorganic Chemistry | en |
| dc.subject | QD Chemistry | en |
| dc.subject | DAS | en |
| dc.subject.lcc | QD | en |
| dc.title | Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides | en |
| dc.type | Journal article | en |
| dc.contributor.institution | University of St Andrews. School of Chemistry | en |
| dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
| dc.identifier.doi | 10.1021/acs.inorgchem.5b00542 | |
| dc.description.status | Peer reviewed | en |
| dc.date.embargoedUntil | 2016-04-22 | |
| dc.identifier.url | http://pubs.acs.org/doi/suppl/10.1021/acs.inorgchem.5b00542 | en |
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