Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides

Thalangamaarachchige, Vidura D.; Unruh, Daniel K.; Cordes, David Bradford; Krempner, Clemens

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dc.contributor.author	Thalangamaarachchige, Vidura D.
dc.contributor.author	Unruh, Daniel K.
dc.contributor.author	Cordes, David Bradford
dc.contributor.author	Krempner, Clemens
dc.date.accessioned	2016-04-22T08:37:20Z
dc.date.available	2016-04-22T08:37:20Z
dc.date.issued	2015-05-04
dc.identifier.citation	Thalangamaarachchige , V D , Unruh , D K , Cordes , D B & Krempner , C 2015 , ' Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides ' , Inorganic Chemistry , vol. 54 , no. 9 , pp. 4189-4191 . https://doi.org/10.1021/acs.inorgchem.5b00542	en
dc.identifier.issn	0020-1669
dc.identifier.other	PURE: 187416375
dc.identifier.other	PURE UUID: 82f864d1-47d8-43d3-ae42-7e0605ea8e23
dc.identifier.other	Scopus: 84929224108
dc.identifier.other	ORCID: /0000-0002-5366-9168/work/28024004
dc.identifier.other	WOS: 000354075600005
dc.identifier.uri	http://hdl.handle.net/10023/8663
dc.description.abstract	The synthesis and structures of the first zwitterionic divalent rare-earth metal silanides of the formula [Si(SiMe2OMe)3-κ3]2M (M-3), where M = Eu, Yb, and Sm, are reported. M-3 compounds feature spirocyclic bicyclooctane structures in which the central rare-earth metal ions are being octahedrally coordinated by six methoxy groups. The reaction of Yb-3 with BPh3 and W(CO)6 respectively generated the trinuclear zwitterions [Ph3BSi(SiMe2OMe)3-κ3]2Yb (Yb-4) and [(CO)5WSi(SiMe2OMe)3-κ3]2Yb (Yb-5) in good yield.
dc.language.iso	eng
dc.relation.ispartof	Inorganic Chemistry	en
dc.rights	Copyright © 2015 American Chemical Society. This document is the Accepted Manuscript version of a Published Work that appeared in final form in Inorganic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://dx.doi.org/10.1021/acs.inorgchem.5b00542	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject.lcc	QD	en
dc.title	Synthesis, structure, and reactivity of zwitterionic divalent rare-earth metal silanides	en
dc.type	Journal article	en
dc.description.version	Postprint	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	https://doi.org/10.1021/acs.inorgchem.5b00542
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2016-04-22
dc.identifier.url	http://pubs.acs.org/doi/suppl/10.1021/acs.inorgchem.5b00542	en

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