Solid-phase synthesis of recyclable diphosphine ligands
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An efficient solid-phase synthetic approach towards diphosphine ligands is demonstrated. This modular method offers facile access to this important class of ligands, in quantitative yield, providing huge potential for ligand fine-tuning. These supported ligands can be efficiently applied in asymmetric catalysis. Moreover, the immobilized catalysts can successfully be recycled multiple times addressing several synthetic and work-up challenges in the field of catalytic chemistry.
Heutz , F , Samuels , M C & Kamer , P C J 2015 , ' Solid-phase synthesis of recyclable diphosphine ligands ' , Catalysis Science & Technology , vol. 5 , no. 6 , pp. 3296-3301 . https://doi.org/10.1039/C5CY00287G
Catalysis Science & Technology
© 2015 the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://dx.doi.org/10.1039/C5CY00287G
DescriptionThe authors thank the European Union (Marie Curie ITN SusPhos, Grant Agreement No. 317404 and COST action PhoSciNet cm08602) for financial support.
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