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Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation

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dc.contributor.authorBurrows, Andrew D.
dc.contributor.authorFisher, Laura C.
dc.contributor.authorMays, Timothy J.
dc.contributor.authorRigby, Sean P.
dc.contributor.authorAshbrook, Sharon E.
dc.contributor.authorDawson, Daniel M.
dc.date.accessioned2016-04-08T23:01:48Z
dc.date.available2016-04-08T23:01:48Z
dc.date.issued2015-09-01
dc.identifier177334196
dc.identifiere5e2d841-ae6e-4fb3-b5b2-906676067210
dc.identifier000359201500020
dc.identifier000359201500020
dc.identifier84938968793
dc.identifier.citationBurrows , A D , Fisher , L C , Mays , T J , Rigby , S P , Ashbrook , S E & Dawson , D M 2015 , ' Post-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formation ' , Journal of Organometallic Chemistry , vol. 792 , pp. 134-138 . https://doi.org/10.1016/j.jorganchem.2015.03.031en
dc.identifier.issn0022-328X
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56638902
dc.identifier.otherORCID: /0000-0002-8110-4535/work/34029114
dc.identifier.urihttps://hdl.handle.net/10023/8588
dc.descriptionThe EPSRC is thanked for financial support.en
dc.description.abstractPost-synthetic Suzuki coupling reactions have been undertaken on the halide-functionalised metal-organic frameworks (MOFs) [Zn4O(bdc-Br)3] (bdc-Br = 2-bromo-1,4-benzenedicarboxylate, IRMOF-2) and [Zn4O(bdc-I)3] (bdc-I = 2-iodo-1,4-benzenedicarboxylate). Although the bulky catalyst employed leads to relatively low conversions, the use of core–shell MOFs demonstrates that the reactions are not confined to the crystal surfaces.
dc.format.extent5
dc.format.extent1984032
dc.language.isoeng
dc.relation.ispartofJournal of Organometallic Chemistryen
dc.subjectMetal-organic frameworken
dc.subjectPost-synthetic modificationen
dc.subjectZincen
dc.subjectPalladiumen
dc.subjectSuzuki couplingen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titlePost-synthetic modification of zinc metal-organic frameworks through palladium- catalysed carbon-carbon bond formationen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.jorganchem.2015.03.031
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-04-09
dc.identifier.urlhttp://www.sciencedirect.com/science/article/pii/S0022328X15001904#appd001en


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