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Conducting olefin metathesis reactions in air : breaking the paradigm

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dc.contributor.authorGuidone, Stefano
dc.contributor.authorSongis, Olivier
dc.contributor.authorNahra, Fady
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2016-03-25T00:01:15Z
dc.date.available2016-03-25T00:01:15Z
dc.date.issued2015
dc.identifier.citationGuidone , S , Songis , O , Nahra , F & Cazin , C S J 2015 , ' Conducting olefin metathesis reactions in air : breaking the paradigm ' , ACS Catalysis , vol. 5 , pp. 2697-2701 . https://doi.org/10.1021/acscatal.5b00197en
dc.identifier.issn2155-5435
dc.identifier.otherPURE: 175344405
dc.identifier.otherPURE UUID: f284c8ec-fa27-45d2-960e-701d15e779f5
dc.identifier.otherScopus: 84929485871
dc.identifier.otherWOS: 000354012200001
dc.identifier.urihttps://hdl.handle.net/10023/8483
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the EC (CP-FP 211468-2 EUMET) for funding.en
dc.description.abstractThe first study of low catalyst loading olefin metathesis reactions in air is reported. TON values of up to 7000 were obtained using non-degassed solvents with commercially available pre-catalysts Caz-1, Hov-II and Ind-II. The simple experimental conditions allow olefin metathesis reactions to be carried out on the benchtop using technical grade solvents in air.
dc.language.isoeng
dc.relation.ispartofACS Catalysisen
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © 2015 American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/doi/abs/10.1021/acscatal.5b00197.en
dc.subjectOlefin metathesisen
dc.subjectHomogeneous catalysisen
dc.subjectRutheniumen
dc.subjectPhosphiteen
dc.subjectAiren
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleConducting olefin metathesis reactions in air : breaking the paradigmen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.sponsorEuropean Commissionen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/acscatal.5b00197
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-03-25
dc.identifier.urlhttp://pubs.acs.org/doi/suppl/10.1021/acscatal.5b00197en
dc.identifier.grantnumberUF100691en
dc.identifier.grantnumberCP-FP 211468-2 EUMETen


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