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dc.contributor.authorOpanasenko, Maksym
dc.contributor.authorShamzhy, Mariya
dc.contributor.authorYu, Fengjiao
dc.contributor.authorZhou, Wuzong
dc.contributor.authorMorris, Russell Edward
dc.contributor.authorCejka, Jiri
dc.identifier.citationOpanasenko , M , Shamzhy , M , Yu , F , Zhou , W , Morris , R E & Cejka , J 2016 , ' Zeolite-derived hybrid materials with adjustable organic pillars ' , Chemical Science , vol. 7 , no. 6 , pp. 3589-3601 .
dc.identifier.otherPURE: 241578377
dc.identifier.otherPURE UUID: c1392cb1-ceb4-4e54-b30b-26c927a5b372
dc.identifier.otherBibtex: urn:7b59b26f94b747a8615e9b8bcebedd56
dc.identifier.otherScopus: 84971264626
dc.identifier.otherORCID: /0000-0001-9752-7076/work/58054997
dc.identifier.otherWOS: 000377262200014
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622077
dc.descriptionM. O. thanks the Czech Science Foundation for the support (13-17593P), J. Č. thanks the Czech Science Foundation for the support of this research (P106/12/G015). R. E. M. thanks the Royal Society and the E.P.S.R.C. (Grants EP/K025112/1 and EP/K005499/1) for funding work in this area.en
dc.description.abstractPorous organic-inorganic materials with tunable textural characteristics were synthesized using the top-down process by intercalating silsesquioxanes and polyhedral oligomeric siloxanes of different types between crystalline zeolite-derived layers. The influence of key parameters such as (i) linker nature (pure hydrocarbon, S-, N-containing); (ii) chain length in alkyl- and aryl bis(trialkoxysilyl) derivatives; (iii) denticity of the organic precursor molecules; (iv) nature and size of side chain in mono(trialkoxysilyl) substrates; (v) rigidity of the chain (saturated vs. unsaturated, aliphatic vs. aromatic); (vi) nature and size of leaving group on the structural and textural properties of formed hybrids was carefully addressed. It was established, that the optimal silsesquioxane appropriate for the formation of zeolite-derived hybrids with high textural characteristics should possess short alkyl or long aryl chains, relatively small leaving groups and denticity larger than 3. Addition of polydentate low-molecular binder improved the structural and textural characteristics of hybrids, especially when using bulky or hydrophilic linkers.
dc.relation.ispartofChemical Scienceen
dc.rightsCopyright 2016 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (
dc.subjectQD Chemistryen
dc.titleZeolite-derived hybrid materials with adjustable organic pillarsen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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