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Novel reaction of 3,4-dibromofuran with azo diesters to give tetrahydropyridazinones
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dc.contributor.author | Aitken, Kati Marianne | |
dc.contributor.author | Aitken, Robert Alan | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.date.accessioned | 2016-03-03T17:10:03Z | |
dc.date.available | 2016-03-03T17:10:03Z | |
dc.date.issued | 2016-02-29 | |
dc.identifier.citation | Aitken , K M , Aitken , R A & Slawin , A M Z 2016 , ' Novel reaction of 3,4-dibromofuran with azo diesters to give tetrahydropyridazinones ' , RSC Advances , vol. 6 , pp. 22969-22972 . https://doi.org/10.1039/C6RA02735K | en |
dc.identifier.issn | 2046-2069 | |
dc.identifier.other | PURE: 241162545 | |
dc.identifier.other | PURE UUID: 74598f76-a9c7-40fa-9538-0338df85255d | |
dc.identifier.other | Scopus: 84960193453 | |
dc.identifier.other | ORCID: /0000-0001-6959-5311/work/34857572 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861604 | |
dc.identifier.other | WOS: 000371716300086 | |
dc.identifier.uri | https://hdl.handle.net/10023/8359 | |
dc.description.abstract | Cycloaddition of 3,4-dibromofuran with azo diesters proceeds by a Diels–Alder reaction followed by a novel rearrangement to give 3,5-dibromotetrahydropyridazin-4-ones. Variable-temperature NMR spectroscopy shows four separate conformations at low temperature attributed to restricted rotation about the carbamate functions. The ethyl compound decomposes upon storage with loss of the carbamate groups and aromatisation to give a simple bromohydroxypyridazinium salt. | |
dc.format.extent | 4 | |
dc.language.iso | eng | |
dc.relation.ispartof | RSC Advances | en |
dc.rights | Copyright 2016 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/) | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Novel reaction of 3,4-dibromofuran with azo diesters to give tetrahydropyridazinones | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/C6RA02735K | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.rsc.org/suppdata/c6/ra/c6ra02735k/c6ra02735k1.pdf | en |
dc.identifier.url | http://www.rsc.org/suppdata/c6/ra/c6ra02735k/c6ra02735k2.cif | en |
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