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dc.contributor.authorGasperini, Danila
dc.contributor.authorCollado-Martinez, Alba
dc.contributor.authorGomez Suarez, Adrian
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2016-02-20T00:12:24Z
dc.date.available2016-02-20T00:12:24Z
dc.date.issued2015-03-27
dc.identifier.citationGasperini , D , Collado-Martinez , A , Gomez Suarez , A , Cordes , D B , Slawin , A M Z & Nolan , S P 2015 , ' Gold-acetonyl complexes : from side-products to valuable synthons ' Chemistry - A European Journal , vol. 21 , no. 14 , pp. 5403-5412 . DOI: 10.1002/chem.201406543en
dc.identifier.issn0947-6539
dc.identifier.otherPURE: 167704064
dc.identifier.otherPURE UUID: e26a3149-2bcd-458c-925b-9b04767ca4da
dc.identifier.otherScopus: 84925082751
dc.identifier.urihttp://hdl.handle.net/10023/8271
dc.identifier.urihttp://onlinelibrary.wiley.com/doi/10.1002/chem.201406543/suppinfoen
dc.descriptionThe ERC (Advanced Investigator Award-FUNCAT), EPSRC and Syngenta are gratefully acknowledged for support. Umicore AG is acknowledged for their generous gift of materials. S.P.N. is a Royal Society Wolfson Research Merit Award holder.en
dc.description.abstractA new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH3)]. The approach capitalizes on the formation of a decomposition product observed in the course of the synthesis of [Au(IPr)(Cl)]. A library of gold acetonyl complexes containing the most common N-heterocyclic carbene (NHC) ligands has been synthesized. These acetonyl complexes are good synthons for the preparation of numerous organogold complexes. Moreover, they have proven to be precatalysts in common gold(I)-catalyzed reactions.en
dc.format.extent10en
dc.language.isoeng
dc.relation.ispartofChemistry - A European Journalen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Gasperini, D., Collado, A., Goméz-Suárez, A., Cordes, D. B., Slawin, A. M. Z. and Nolan, S. P. (2015), Gold–Acetonyl Complexes: From Side-Products to Valuable Synthons. Chem. Eur. J., which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201406543/abstracten
dc.subjectGolden
dc.subjectAcetonylen
dc.subjectN-heterocyclic carbeneen
dc.subjectOrganogold complexesen
dc.subjectCatalysisen
dc.subjectCarbenesen
dc.subjectOrganogolden
dc.subjectHomogeneous catalysisen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleGold-acetonyl complexes : from side-products to valuable synthonsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/chem.201406543
dc.description.statusPeer revieweden
dc.date.embargoedUntil20-02-20


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