Gold-acetonyl complexes : from side-products to valuable synthons

Gasperini, Danila; Collado-Martinez, Alba; Gomez Suarez, Adrian; Cordes, David Bradford; Slawin, Alexandra Martha Zoya; Nolan, Steven Patrick

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dc.contributor.author	Gasperini, Danila
dc.contributor.author	Collado-Martinez, Alba
dc.contributor.author	Gomez Suarez, Adrian
dc.contributor.author	Cordes, David Bradford
dc.contributor.author	Slawin, Alexandra Martha Zoya
dc.contributor.author	Nolan, Steven Patrick
dc.date.accessioned	2016-02-20T00:12:24Z
dc.date.available	2016-02-20T00:12:24Z
dc.date.issued	2015-03-27
dc.identifier.citation	Gasperini , D , Collado-Martinez , A , Gomez Suarez , A , Cordes , D B , Slawin , A M Z & Nolan , S P 2015 , ' Gold-acetonyl complexes : from side-products to valuable synthons ' , Chemistry - A European Journal , vol. 21 , no. 14 , pp. 5403-5412 . https://doi.org/10.1002/chem.201406543	en
dc.identifier.issn	0947-6539
dc.identifier.other	PURE: 167704064
dc.identifier.other	PURE UUID: e26a3149-2bcd-458c-925b-9b04767ca4da
dc.identifier.other	Scopus: 84925082751
dc.identifier.other	ORCID: /0000-0002-5366-9168/work/28024005
dc.identifier.other	ORCID: /0000-0002-9527-6418/work/56861894
dc.identifier.other	WOS: 000352504500020
dc.identifier.uri	https://hdl.handle.net/10023/8271
dc.description	The ERC (Advanced Investigator Award-FUNCAT), EPSRC and Syngenta are gratefully acknowledged for support. Umicore AG is acknowledged for their generous gift of materials. S.P.N. is a Royal Society Wolfson Research Merit Award holder.	en
dc.description.abstract	A new synthetic strategy was devised leading to the formation of complexes, such as [Au(IPr)(CH2COCH3)]. The approach capitalizes on the formation of a decomposition product observed in the course of the synthesis of [Au(IPr)(Cl)]. A library of gold acetonyl complexes containing the most common N-heterocyclic carbene (NHC) ligands has been synthesized. These acetonyl complexes are good synthons for the preparation of numerous organogold complexes. Moreover, they have proven to be precatalysts in common gold(I)-catalyzed reactions.
dc.format.extent	10
dc.language.iso	eng
dc.relation.ispartof	Chemistry - A European Journal	en
dc.rights	© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Gasperini, D., Collado, A., Goméz-Suárez, A., Cordes, D. B., Slawin, A. M. Z. and Nolan, S. P. (2015), Gold–Acetonyl Complexes: From Side-Products to Valuable Synthons. Chem. Eur. J., which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1002/chem.201406543/abstract	en
dc.subject	Gold	en
dc.subject	Acetonyl	en
dc.subject	N-heterocyclic carbene	en
dc.subject	Organogold complexes	en
dc.subject	Catalysis	en
dc.subject	Carbenes	en
dc.subject	Organogold	en
dc.subject	Homogeneous catalysis	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject.lcc	QD	en
dc.title	Gold-acetonyl complexes : from side-products to valuable synthons	en
dc.type	Journal article	en
dc.contributor.sponsor	European Research Council	en
dc.contributor.sponsor	EPSRC	en
dc.contributor.sponsor	EPSRC	en
dc.description.version	Postprint	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	https://doi.org/10.1002/chem.201406543
dc.description.status	Peer reviewed	en
dc.date.embargoedUntil	2016-02-20
dc.identifier.url	http://onlinelibrary.wiley.com/doi/10.1002/chem.201406543/suppinfo	en
dc.identifier.grantnumber	FP7-227817 FUNCAT	en
dc.identifier.grantnumber	EP/K031252/1	en
dc.identifier.grantnumber	EP/K039210/1	en

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