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Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interaction

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dc.contributor.authorNordheider, Andreas
dc.contributor.authorHupf, Emanuel
dc.contributor.authorChalmers, Brian Alexander
dc.contributor.authorKnight, Fergus Ross
dc.contributor.authorBuehl, Michael
dc.contributor.authorMebs, Stefan
dc.contributor.authorChęcińska, Liliana
dc.contributor.authorLork, Enno
dc.contributor.authorSanz Camacho, Paula
dc.contributor.authorAshbrook, Sharon Elizabeth
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorBeckmann, Jens
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2016-02-18T00:12:32Z
dc.date.available2016-02-18T00:12:32Z
dc.date.issued2015-03-02
dc.identifier163999573
dc.identifier7b7fe8a2-1396-43e3-8ba3-fec088ff27ba
dc.identifier84924075989
dc.identifier000350391600042
dc.identifier25692668
dc.identifier.citationNordheider , A , Hupf , E , Chalmers , B A , Knight , F R , Buehl , M , Mebs , S , Chęcińska , L , Lork , E , Sanz Camacho , P , Ashbrook , S E , Athukorala Arachchige , K S , Cordes , D B , Slawin , A M Z , Beckmann , J & Woollins , J D 2015 , ' Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interaction ' , Inorganic Chemistry , vol. 54 , no. 5 , pp. 2435-2446 . https://doi.org/10.1021/ic503056zen
dc.identifier.issn0020-1669
dc.identifier.otherORCID: /0000-0002-1095-7143/work/48131776
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024008
dc.identifier.otherORCID: /0000-0002-2999-2272/work/55901231
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56638968
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861782
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779183
dc.identifier.urihttps://hdl.handle.net/10023/8251
dc.descriptionThe authors are thankful to the EPSRC, the EPSRC National Mass Spectrometry Service Centre (NMSSC) Swansea, the School of Chemistry St. Andrews, and EaStCHEM for support.en
dc.description.abstractA series of peri-substituted phosphorus-tellurium systems R’Te–Acenap–PR2 (R’ = Ph, p-An, Nap, Mes, Tip; R = iPr, Ph) exhibiting large “through space” spin-spin coupling constants and the “onset” of three-centre four-electron type interactions are presented. The influence of the substituents at the phosphorus and tellurium atoms as well as their behavior upon oxidation (with S, Se) or metal-coordination (Pt, Au) is discussed using NMR spectroscopy, single crystal X-ray diffraction, and advanced DFT studies including NBO, AIM and ELI-D analyses.
dc.format.extent1142569
dc.format.extent947014
dc.language.isoeng
dc.relation.ispartofInorganic Chemistryen
dc.subjectPeri-substitutionen
dc.subjectPhosphorus-telluriumen
dc.subjectThrough-space spin-spin couplingen
dc.subjectAcenaphtheneen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titlePeri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interactionen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1021/ic503056z
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-02-18
dc.identifier.urlhttp://pubs.acs.org/doi/suppl/10.1021/ic503056zen
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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