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dc.contributor.authorNordheider, Andreas
dc.contributor.authorHüll, Katharina
dc.contributor.authorAthukorala Arachchige, Kasun Sankalpa
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorThirumoorthi, Ramalingam
dc.contributor.authorChivers, Tristram
dc.date.accessioned2016-02-07T00:12:36Z
dc.date.available2016-02-07T00:12:36Z
dc.date.issued2015-03-28
dc.identifier.citationNordheider , A , Hüll , K , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D , Thirumoorthi , R & Chivers , T 2015 , ' Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P 2 N 2 -supported anions ' , Dalton Transactions , vol. 44 , no. 12 , pp. 5338-5346 . https://doi.org/10.1039/C5DT00159Een
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 166227324
dc.identifier.otherPURE UUID: 4a1d35f9-f40a-49e9-87f1-8c15840b01b4
dc.identifier.otherScopus: 84924859655
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861551
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779180
dc.identifier.otherWOS: 000351439200013
dc.identifier.urihttp://hdl.handle.net/10023/8166
dc.descriptionFinancial support from the EPSRC and NSERC (Canada) is acknowledged.en
dc.description.abstractMetathetical reactions of alkali–metal derivatives of the dianion [tBuN(Se)P(μ-NtBu)2P(Se)NtBu]2− (2Se2−) with Ag(NHC)Cl, Ag[BF4], AuCl(THT) and HgCl2, as well as the reaction of 2S2− with AuCl(THT) were investigated. The observed products all incorporate the monoprotonated ligands 2SeH− or 2SH− in a variety of structural arrangements around the metal centres, including tetrameric and trimeric macrocycles [Ag and Au (E = Se)], a ladder (Au, E = S) and a spirocycle (Hg); the ladder contains both the dianion 2S2− and the monoanion 2SH− as ligands linking three Au2 units. All complexes have been characterised in the solid state by single crystal X-ray analyses and in solution by multinuclear (1H, 31P and 77Se) NMR spectra.
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright 2015, the Authors. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C5DT00159Een
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSpirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anionsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5DT00159E
dc.description.statusPeer revieweden
dc.date.embargoedUntil2016-02-07
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/dt/c5dt00159e/c5dt00159e1.pdfen
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/dt/c5dt00159e/c5dt00159e2.cifen


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