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Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anions
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dc.contributor.author | Nordheider, Andreas | |
dc.contributor.author | Hüll, Katharina | |
dc.contributor.author | Athukorala Arachchige, Kasun Sankalpa | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.contributor.author | Thirumoorthi, Ramalingam | |
dc.contributor.author | Chivers, Tristram | |
dc.date.accessioned | 2016-02-07T00:12:36Z | |
dc.date.available | 2016-02-07T00:12:36Z | |
dc.date.issued | 2015-03-28 | |
dc.identifier | 166227324 | |
dc.identifier | 4a1d35f9-f40a-49e9-87f1-8c15840b01b4 | |
dc.identifier | 84924859655 | |
dc.identifier | 000351439200013 | |
dc.identifier.citation | Nordheider , A , Hüll , K , Athukorala Arachchige , K S , Slawin , A M Z , Woollins , J D , Thirumoorthi , R & Chivers , T 2015 , ' Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P 2 N 2 -supported anions ' , Dalton Transactions , vol. 44 , no. 12 , pp. 5338-5346 . https://doi.org/10.1039/C5DT00159E | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861551 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779180 | |
dc.identifier.uri | https://hdl.handle.net/10023/8166 | |
dc.description | Financial support from the EPSRC and NSERC (Canada) is acknowledged. | en |
dc.description.abstract | Metathetical reactions of alkali–metal derivatives of the dianion [tBuN(Se)P(μ-NtBu)2P(Se)NtBu]2− (2Se2−) with Ag(NHC)Cl, Ag[BF4], AuCl(THT) and HgCl2, as well as the reaction of 2S2− with AuCl(THT) were investigated. The observed products all incorporate the monoprotonated ligands 2SeH− or 2SH− in a variety of structural arrangements around the metal centres, including tetrameric and trimeric macrocycles [Ag and Au (E = Se)], a ladder (Au, E = S) and a spirocycle (Hg); the ladder contains both the dianion 2S2− and the monoanion 2SH− as ligands linking three Au2 units. All complexes have been characterised in the solid state by single crystal X-ray analyses and in solution by multinuclear (1H, 31P and 77Se) NMR spectra. | |
dc.format.extent | 977754 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anions | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/C5DT00159E | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2016-02-07 | |
dc.identifier.url | http://www.rsc.org/suppdata/c5/dt/c5dt00159e/c5dt00159e1.pdf | en |
dc.identifier.url | http://www.rsc.org/suppdata/c5/dt/c5dt00159e/c5dt00159e2.cif | en |
dc.identifier.grantnumber | EP/K503940/1 | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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