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V2O2F4(H2O)2·H2O: a new V4+ layer structure related to VOF3

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dc.contributor.authorBlack, Cameron
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2016-01-25T15:40:02Z
dc.date.available2016-01-25T15:40:02Z
dc.date.issued2016-01
dc.identifier240325520
dc.identifier61e7b692-9dfc-48e5-90ae-9bec0b1c64bf
dc.identifier84954323723
dc.identifier000367827500013
dc.identifier.citationBlack , C & Lightfoot , P 2016 , ' V 2 O 2 F 4 (H 2 O) 2 ·H 2 O: a new V 4+ layer structure related to VOF 3 ' , Acta Crystallographica Section C: Crystal Structure Communications , vol. 72 , no. 1 , pp. 80-83 . https://doi.org/10.1107/S2053229615024122en
dc.identifier.issn0108-2701
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464490
dc.identifier.urihttps://hdl.handle.net/10023/8077
dc.descriptionThe authors thank EPSRC for a DTA studentship (EP/P505097/1) to CB.en
dc.description.abstractThe title compound, V2O2F4(H2O)2·H2O, (I), features a new infinite, V4+-containing, two-dimensional layer, comprised of fluorine bridged corner-sharing and edge-sharing VOF4(H2O) octahedral building units. Synthesis was carried out under solvothermal conditions. The V4+ centre exhibits a typical off-centring, with a short V=O bond and elongated trans V—F bond. Hydrogen bonded water molecules occur between the layers. The structure is related to previously reported vana- dium oxyfluoride structures, in particular the same layer topology is seen in VOF3.
dc.format.extent175693
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communicationsen
dc.subjectV4+ layer structureen
dc.subjectVIV oxyfluoridesen
dc.subjectFrustrated magnetsen
dc.subjectCrystal structureen
dc.subjectIonic liquidsen
dc.subjectFluorine bridgingen
dc.subjectSolvothermal conditionsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleV2O2F4(H2O)2·H2O: a new V4+ layer structure related to VOF3en
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1107/S2053229615024122
dc.description.statusPeer revieweden


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