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V2O2F4(H2O)2·H2O: a new V4+ layer structure related to VOF3

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dc.contributor.authorBlack, Cameron
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2016-01-25T15:40:02Z
dc.date.available2016-01-25T15:40:02Z
dc.date.issued2016-01
dc.identifier.citationBlack , C & Lightfoot , P 2016 , ' V 2 O 2 F 4 (H 2 O) 2 ·H 2 O: a new V 4+ layer structure related to VOF 3 ' , Acta Crystallographica Section C: Crystal Structure Communications , vol. 72 , no. 1 , pp. 80-83 . https://doi.org/10.1107/S2053229615024122en
dc.identifier.issn0108-2701
dc.identifier.otherPURE: 240325520
dc.identifier.otherPURE UUID: 61e7b692-9dfc-48e5-90ae-9bec0b1c64bf
dc.identifier.otherScopus: 84954323723
dc.identifier.otherORCID: /0000-0001-7048-3982/work/59464490
dc.identifier.otherWOS: 000367827500013
dc.identifier.urihttps://hdl.handle.net/10023/8077
dc.descriptionThe authors thank EPSRC for a DTA studentship (EP/P505097/1) to CB.en
dc.description.abstractThe title compound, V2O2F4(H2O)2·H2O, (I), features a new infinite, V4+-containing, two-dimensional layer, comprised of fluorine bridged corner-sharing and edge-sharing VOF4(H2O) octahedral building units. Synthesis was carried out under solvothermal conditions. The V4+ centre exhibits a typical off-centring, with a short V=O bond and elongated trans V—F bond. Hydrogen bonded water molecules occur between the layers. The structure is related to previously reported vana- dium oxyfluoride structures, in particular the same layer topology is seen in VOF3.
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section C: Crystal Structure Communicationsen
dc.rightsCopyright 2016 International Union of Crystallography. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1107/S2053229615024122en
dc.subjectV4+ layer structureen
dc.subjectVIV oxyfluoridesen
dc.subjectFrustrated magnetsen
dc.subjectCrystal structureen
dc.subjectIonic liquidsen
dc.subjectFluorine bridgingen
dc.subjectSolvothermal conditionsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleV2O2F4(H2O)2·H2O: a new V4+ layer structure related to VOF3en
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1107/S2053229615024122
dc.description.statusPeer revieweden


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