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Platinum complexes of aromatic selenolates
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dc.contributor.author | Fuller, Amy | |
dc.contributor.author | Knight, Fergus Ross | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.date.accessioned | 2016-01-15T15:10:08Z | |
dc.date.available | 2016-01-15T15:10:08Z | |
dc.date.issued | 2010-09 | |
dc.identifier | 4638044 | |
dc.identifier | 31de36f4-270b-4f13-95af-7504ef790f62 | |
dc.identifier | 000282913000018 | |
dc.identifier | 77956520107 | |
dc.identifier.citation | Fuller , A , Knight , F R , Slawin , A M Z & Woollins , J D 2010 , ' Platinum complexes of aromatic selenolates ' , European Journal of Inorganic Chemistry , vol. 2010 , no. 25 , pp. 4034-4043 . https://doi.org/10.1002/ejic.201000357 | en |
dc.identifier.issn | 1434-1948 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56862101 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779245 | |
dc.identifier.uri | https://hdl.handle.net/10023/8027 | |
dc.description.abstract | Several synthetic methods are used to prepare naphthalene-based aromatic 1,2-diselenoles. A new one-pot synthesis starting from naphthalene is used to produce theknown compound naphtho[1,8-c,d][1,2]diselenole (Se2naph).Friedel–Crafts alkylation is used on Se2naph to substitute either one tert-butyl group to form 2-tert-butylnaphtho[1,8-c,d][1,2]diselenole (mt-Se2naph) or two tert-butyl groups to form 2,7-di-tert-butylnaphtho[1,8-c,d][1,2]diselenole (dt-Se2naph). Bromination of mt-Se2naph results in dibromination of the naphthalene ring, rather than reaction at selenium, to give 4,7-dibromo-2-tert-butylnaphtho[1,8-c,d][1,2]diselenole (mt-Se2naphBr2). Reduction of the Se–Se bond in Se2naph, mt-Se2naph, dibenzo[c,e][1,2]diselenine (dibenzSe2), or diphenyl diselenide (Se2Ph2) with LiBEt3 H, followed by in-situ addition of [PtCl2{P(OPh)3}2] yields the four-coordinate mono- and dinuclear platinum(II) bis(phosphite) complexes [Pt(Se2naph){P(OPh)3}2] ( 1 ), [Pt(mt-Se2naph){P(OPh)3}2] ( 2 ), [Pt2(dibenzSe2)2{P(OPh)3}2] ( 3 ), cis-[Pt(SePh)2{P(OPh)3}2] ( 4 ), and trans-[Pt2(SePh)4{P(OPh)3}2] ( 5 ). | |
dc.format.extent | 10 | |
dc.format.extent | 876213 | |
dc.language.iso | eng | |
dc.relation.ispartof | European Journal of Inorganic Chemistry | en |
dc.subject | Platinum | en |
dc.subject | Selenium | en |
dc.subject | Heterocycles | en |
dc.subject | Polyaromatic hydrocarbon ligands | en |
dc.subject | Crystal-structure | en |
dc.subject | Naphthalenes | en |
dc.subject | TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM | en |
dc.subject | Sulfur | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Platinum complexes of aromatic selenolates | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | 10.1002/ejic.201000357 | |
dc.description.status | Peer reviewed | en |
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