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dc.contributor.authorFuller, Amy
dc.contributor.authorKnight, Fergus Ross
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2016-01-15T15:10:08Z
dc.date.available2016-01-15T15:10:08Z
dc.date.issued2010-09
dc.identifier.citationFuller , A , Knight , F R , Slawin , A M Z & Woollins , J D 2010 , ' Platinum complexes of aromatic selenolates ' , European Journal of Inorganic Chemistry , vol. 2010 , no. 25 , pp. 4034-4043 . https://doi.org/10.1002/ejic.201000357en
dc.identifier.issn1434-1948
dc.identifier.otherPURE: 4638044
dc.identifier.otherPURE UUID: 31de36f4-270b-4f13-95af-7504ef790f62
dc.identifier.otherWOS: 000282913000018
dc.identifier.otherScopus: 77956520107
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862101
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779245
dc.identifier.urihttps://hdl.handle.net/10023/8027
dc.description.abstractSeveral synthetic methods are used to prepare naphthalene-based aromatic 1,2-diselenoles. A new one-pot synthesis starting from naphthalene is used to produce theknown compound naphtho[1,8-c,d][1,2]diselenole (Se2naph).Friedel–Crafts alkylation is used on Se2naph to substitute either one tert-butyl group to form 2-tert-butylnaphtho[1,8-c,d][1,2]diselenole (mt-Se2naph) or two tert-butyl groups to form 2,7-di-tert-butylnaphtho[1,8-c,d][1,2]diselenole (dt-Se2naph). Bromination of mt-Se2naph results in dibromination of the naphthalene ring, rather than reaction at selenium, to give 4,7-dibromo-2-tert-butylnaphtho[1,8-c,d][1,2]diselenole (mt-Se2naphBr2). Reduction of the Se–Se bond in Se2naph, mt-Se2naph, dibenzo[c,e][1,2]diselenine (dibenzSe2), or diphenyl diselenide (Se2Ph2) with LiBEt3 H, followed by in-situ addition of [PtCl2{P(OPh)3}2] yields the four-coordinate mono- and dinuclear platinum(II) bis(phosphite) complexes [Pt(Se2naph){P(OPh)3}2] ( 1 ), [Pt(mt-Se2naph){P(OPh)3}2] ( 2 ), [Pt2(dibenzSe2)2{P(OPh)3}2] ( 3 ), cis-[Pt(SePh)2{P(OPh)3}2] ( 4 ), and trans-[Pt2(SePh)4{P(OPh)3}2] ( 5 ).
dc.format.extent10
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.rightsCopyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1002/ejic.201000357en
dc.subjectPlatinumen
dc.subjectSeleniumen
dc.subjectHeterocyclesen
dc.subjectPolyaromatic hydrocarbon ligandsen
dc.subjectCrystal-structureen
dc.subjectNaphthalenesen
dc.subjectTETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUMen
dc.subjectSulfuren
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titlePlatinum complexes of aromatic selenolatesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doihttps://doi.org/10.1002/ejic.201000357
dc.description.statusPeer revieweden


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