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Platinum complexes of aromatic selenolates
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dc.contributor.author | Fuller, Amy | |
dc.contributor.author | Knight, Fergus Ross | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.date.accessioned | 2016-01-15T15:10:08Z | |
dc.date.available | 2016-01-15T15:10:08Z | |
dc.date.issued | 2010-09 | |
dc.identifier.citation | Fuller , A , Knight , F R , Slawin , A M Z & Woollins , J D 2010 , ' Platinum complexes of aromatic selenolates ' , European Journal of Inorganic Chemistry , vol. 2010 , no. 25 , pp. 4034-4043 . https://doi.org/10.1002/ejic.201000357 | en |
dc.identifier.issn | 1434-1948 | |
dc.identifier.other | PURE: 4638044 | |
dc.identifier.other | PURE UUID: 31de36f4-270b-4f13-95af-7504ef790f62 | |
dc.identifier.other | WOS: 000282913000018 | |
dc.identifier.other | Scopus: 77956520107 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56862101 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779245 | |
dc.identifier.uri | https://hdl.handle.net/10023/8027 | |
dc.description.abstract | Several synthetic methods are used to prepare naphthalene-based aromatic 1,2-diselenoles. A new one-pot synthesis starting from naphthalene is used to produce theknown compound naphtho[1,8-c,d][1,2]diselenole (Se2naph).Friedel–Crafts alkylation is used on Se2naph to substitute either one tert-butyl group to form 2-tert-butylnaphtho[1,8-c,d][1,2]diselenole (mt-Se2naph) or two tert-butyl groups to form 2,7-di-tert-butylnaphtho[1,8-c,d][1,2]diselenole (dt-Se2naph). Bromination of mt-Se2naph results in dibromination of the naphthalene ring, rather than reaction at selenium, to give 4,7-dibromo-2-tert-butylnaphtho[1,8-c,d][1,2]diselenole (mt-Se2naphBr2). Reduction of the Se–Se bond in Se2naph, mt-Se2naph, dibenzo[c,e][1,2]diselenine (dibenzSe2), or diphenyl diselenide (Se2Ph2) with LiBEt3 H, followed by in-situ addition of [PtCl2{P(OPh)3}2] yields the four-coordinate mono- and dinuclear platinum(II) bis(phosphite) complexes [Pt(Se2naph){P(OPh)3}2] ( 1 ), [Pt(mt-Se2naph){P(OPh)3}2] ( 2 ), [Pt2(dibenzSe2)2{P(OPh)3}2] ( 3 ), cis-[Pt(SePh)2{P(OPh)3}2] ( 4 ), and trans-[Pt2(SePh)4{P(OPh)3}2] ( 5 ). | |
dc.format.extent | 10 | |
dc.language.iso | eng | |
dc.relation.ispartof | European Journal of Inorganic Chemistry | en |
dc.rights | Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://dx.doi.org/10.1002/ejic.201000357 | en |
dc.subject | Platinum | en |
dc.subject | Selenium | en |
dc.subject | Heterocycles | en |
dc.subject | Polyaromatic hydrocarbon ligands | en |
dc.subject | Crystal-structure | en |
dc.subject | Naphthalenes | en |
dc.subject | TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM | en |
dc.subject | Sulfur | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Platinum complexes of aromatic selenolates | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.identifier.doi | https://doi.org/10.1002/ejic.201000357 | |
dc.description.status | Peer reviewed | en |
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