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dc.contributor.authorO’Brien, Cameron
dc.contributor.authorWong, Michael Yin
dc.contributor.authorCordes, David Bradford
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorZysman-Colman, Eli
dc.identifier.citationO’Brien , C , Wong , M Y , Cordes , D B , Slawin , A M Z & Zysman-Colman , E 2015 , ' Cationic platinum(II) complexes bearing Aryl-BIAN ligands : synthesis, structural and optoelectronic characterization ' , Organometallics , vol. 34 , no. 1 , pp. 13-22 .
dc.identifier.otherPURE: 160126120
dc.identifier.otherPURE UUID: 75359852-3fe4-4a5c-8d1e-b0f2208e2f48
dc.identifier.otherWOS: 000347864300003
dc.identifier.otherScopus: 84921048185
dc.identifier.otherORCID: /0000-0002-5366-9168/work/28024017
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639070
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861547
dc.description.abstractFive cationic platinum(II) complexes bearing a 2-(3’-substituted-aryl)pyridine cyclometalating ligand (C^N) and a neutral Ar-BIAN ligand have been synthesized: [Pt(ppy)(PhBIAN)]PF6, 1, [Pt(3Fppy)(PhBIAN)]PF6, 2, [Pt(3MeOppy)(PhBIAN)]PF6, 3, [Pt(3MeOppy)( 4-FPhBIAN)]PF6, 4, [Pt(ppy)(4-MeOPhBIAN)]PF6, 5. All complexes have been characterized by NMR spectroscopy and mass spectrometry. Complexes 2 and 3 have been characterized by X-Ray crystallography. Structure-property relationships were established from UV-Visible spectroscopy and cyclic voltammetry studies. Interestingly, we found that when both the C^N and the Aryl-BIAN ligands contained electron-donating MeO groups the absorption spectrum for the platinum complex extended out to 650 nm. The electrochemical studies of these complexes established that they are electronically compatible dye-molecules for dye-sensitized solar cells.
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, 2014 © American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see
dc.subjectQD Chemistryen
dc.titleCationic platinum(II) complexes bearing Aryl-BIAN ligands : synthesis, structural and optoelectronic characterizationen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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