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A Silver(I) Iodide Complex of a Tellurophosphorane

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dc.contributor.authorNordheider, Andreas
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorChivers, Tristram
dc.date.accessioned2015-11-26T00:12:18Z
dc.date.available2015-11-26T00:12:18Z
dc.date.issued2015-02
dc.identifier168684269
dc.identifier1372e832-357d-4879-a77c-3cc9f0528707
dc.identifier84922788689
dc.identifier000351444500043
dc.identifier.citationNordheider , A , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' A Silver(I) Iodide Complex of a Tellurophosphorane ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 641 , no. 2 , pp. 405-407 . https://doi.org/10.1002/zaac.201400452en
dc.identifier.issn0044-2313
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862087
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779187
dc.identifier.urihttps://hdl.handle.net/10023/7851
dc.descriptionThe authors acknowledge the EPSRC and NSERC (Canada) for support.en
dc.description.abstractThe formation and structural characterization of the first coordination complex of the tellurophosphorane [tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu] are presented. The silver(I) iodide complex {(I)Ag[tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu]3} (2) was isolated from the reaction of [Li(TMEDA)]2[tBuN(Te)P(μ-NtBu)2P(Te)NtBu)] (1) with AgI in toluene and characterized by X-ray analysis and multinuclear NMR spectroscopy. Complex 2 is comprised of three tellurophosphorane ligands coordinated to AgI in a distorted tetrahedral arrangement [102.90(3)–114.51(5)o]. The P=Te bond lengths of 2.3883(13)–2.4043(17) Å in 2 are slightly elongated compared to those in the free ligand.
dc.format.extent477394
dc.language.isoeng
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen
dc.subjectPhosphorusen
dc.subjectTelluriumen
dc.subjectSilveren
dc.subjectCyclodiphosphazaneen
dc.subjectCrystal structureen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleA Silver(I) Iodide Complex of a Tellurophosphoraneen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/zaac.201400452
dc.description.statusPeer revieweden
dc.date.embargoedUntil2015-11-26
dc.identifier.grantnumberEP/K503940/1en
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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