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A Silver(I) Iodide Complex of a Tellurophosphorane

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dc.contributor.authorNordheider, Andreas
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.contributor.authorChivers, Tristram
dc.date.accessioned2015-11-26T00:12:18Z
dc.date.available2015-11-26T00:12:18Z
dc.date.issued2015-02
dc.identifier.citationNordheider , A , Slawin , A M Z , Woollins , J D & Chivers , T 2015 , ' A Silver(I) Iodide Complex of a Tellurophosphorane ' , Zeitschrift für Anorganische und Allgemeine Chemie , vol. 641 , no. 2 , pp. 405-407 . https://doi.org/10.1002/zaac.201400452en
dc.identifier.issn0044-2313
dc.identifier.otherPURE: 168684269
dc.identifier.otherPURE UUID: 1372e832-357d-4879-a77c-3cc9f0528707
dc.identifier.otherScopus: 84922788689
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862087
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779187
dc.identifier.otherWOS: 000351444500043
dc.identifier.urihttps://hdl.handle.net/10023/7851
dc.descriptionThe authors acknowledge the EPSRC and NSERC (Canada) for support.en
dc.description.abstractThe formation and structural characterization of the first coordination complex of the tellurophosphorane [tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu] are presented. The silver(I) iodide complex {(I)Ag[tBu(H)NP(μ-NtBu)2P(Te)N(H)tBu]3} (2) was isolated from the reaction of [Li(TMEDA)]2[tBuN(Te)P(μ-NtBu)2P(Te)NtBu)] (1) with AgI in toluene and characterized by X-ray analysis and multinuclear NMR spectroscopy. Complex 2 is comprised of three tellurophosphorane ligands coordinated to AgI in a distorted tetrahedral arrangement [102.90(3)–114.51(5)o]. The P=Te bond lengths of 2.3883(13)–2.4043(17) Å in 2 are slightly elongated compared to those in the free ligand.
dc.language.isoeng
dc.relation.ispartofZeitschrift für Anorganische und Allgemeine Chemieen
dc.rightsCopyright © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Nordheider, A., Slawin, A. M. Z., Woollins, J. D. and Chivers, T. (2015), A Silver(I) Iodide Complex of a Tellurophosphorane. Z. anorg. allg. Chem., 641: 405–407, which has been published in final form at http://dx.doi.org/10.1002/zaac.201400452en
dc.subjectPhosphorusen
dc.subjectTelluriumen
dc.subjectSilveren
dc.subjectCyclodiphosphazaneen
dc.subjectCrystal structureen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleA Silver(I) Iodide Complex of a Tellurophosphoraneen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/zaac.201400452
dc.description.statusPeer revieweden
dc.date.embargoedUntil2015-11-26
dc.identifier.grantnumberEP/K503940/1en
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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