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Coordination polymers of ZnII and 5-methoxy isophthalate

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dc.contributor.authorMcCormick, Laura Jayne
dc.contributor.authorMorris, Samuel Alexander
dc.contributor.authorTeat, Simon J.
dc.contributor.authorMcPherson, Matthew Joseph
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorMorris, Russell Edward
dc.date.accessioned2015-11-06T12:10:06Z
dc.date.available2015-11-06T12:10:06Z
dc.date.issued2015-10-28
dc.identifier.citationMcCormick , L J , Morris , S A , Teat , S J , McPherson , M J , Slawin , A M Z & Morris , R E 2015 , ' Coordination polymers of Zn II and 5-methoxy isophthalate ' , Dalton Transactions , vol. 44 , no. 40 , pp. 17686-17695 . https://doi.org/10.1039/C5DT02924Den
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 219347483
dc.identifier.otherPURE UUID: 3d2bb658-4aa1-473d-a689-84828499fe07
dc.identifier.otherBibtex: urn:0573a204a82cafdeff5ee2f004fff3cd
dc.identifier.otherScopus: 84943529959
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861705
dc.identifier.otherWOS: 000362362500027
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622115
dc.identifier.urihttps://hdl.handle.net/10023/7751
dc.descriptionThis work was funded by the British Heart Foundation (NH/11/8/29253) and the EPSRC (EP/K005499/1).en
dc.description.abstractSolvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright 2015 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleCoordination polymers of ZnII and 5-methoxy isophthalateen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorBritish Councilen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5DT02924D
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/dt/c5dt02924d/c5dt02924d1.pdfen
dc.identifier.grantnumberEP/K005499/1en
dc.identifier.grantnumberNH/11/8/29253en
dc.identifier.grantnumberEP/K031252/1en
dc.identifier.grantnumberEP/K039210/1en


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