Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorMcCormick, Laura Jayne
dc.contributor.authorMorris, Samuel Alexander
dc.contributor.authorTeat, Simon J.
dc.contributor.authorMcPherson, Matthew Joseph
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorMorris, Russell Edward
dc.date.accessioned2015-11-06T12:10:06Z
dc.date.available2015-11-06T12:10:06Z
dc.date.issued2015-10-28
dc.identifier.citationMcCormick , L J , Morris , S A , Teat , S J , McPherson , M J , Slawin , A M Z & Morris , R E 2015 , ' Coordination polymers of Zn II and 5-methoxy isophthalate ' , Dalton Transactions , vol. 44 , no. 40 , pp. 17686-17695 . https://doi.org/10.1039/C5DT02924Den
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 219347483
dc.identifier.otherPURE UUID: 3d2bb658-4aa1-473d-a689-84828499fe07
dc.identifier.otherBibtex: urn:0573a204a82cafdeff5ee2f004fff3cd
dc.identifier.otherScopus: 84943529959
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861705
dc.identifier.otherWOS: 000362362500027
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622115
dc.identifier.urihttp://hdl.handle.net/10023/7751
dc.descriptionThis work was funded by the British Heart Foundation (NH/11/8/29253) and the EPSRC (EP/K005499/1).en
dc.description.abstractSolvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright 2015 the Authors. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).en
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleCoordination polymers of ZnII and 5-methoxy isophthalateen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5DT02924D
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/dt/c5dt02924d/c5dt02924d1.pdfen


This item appears in the following Collection(s)

Show simple item record