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Ruthenium indenylidene "1st generation" olefin metathesis catalysts containing triisopropyl phosphite

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dc.contributor.authorGuidone, Stefano
dc.contributor.authorNahra, Fady
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorCazin, Catherine S.J.
dc.date.accessioned2015-10-05T08:40:02Z
dc.date.available2015-10-05T08:40:02Z
dc.date.issued2015-09-01
dc.identifier221606711
dc.identifierad138f58-0e40-4307-8808-0dbf461520b8
dc.identifier000360423800001
dc.identifier84962437283
dc.identifier000360423800001
dc.identifier.citationGuidone , S , Nahra , F , Slawin , A M Z & Cazin , C S J 2015 , ' Ruthenium indenylidene "1 st generation" olefin metathesis catalysts containing triisopropyl phosphite ' , Beilstein Journal of Organic Chemistry , vol. 11 , pp. 1520-1527 . https://doi.org/10.3762/bjoc.11.166en
dc.identifier.issn1860-5397
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861405
dc.identifier.urihttps://hdl.handle.net/10023/7594
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC) and the EC (CP-FP 211468-2 EUMET) for funding.en
dc.description.abstractThe reaction of triisopropyl phosphite with phosphine-based indenylidene pre-catalysts affords “1st generation” cis-complexes. These have been used in olefin metathesis reactions. The cis-Ru species exhibit noticeable differences with the trans-Ru parent complexes in terms of structure, thermal stability and reactivity. Experimental data underline the importance of synergistic effects between phosphites and L-type ligands.
dc.format.extent8
dc.format.extent967532
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.subject1st generationen
dc.subjectIndenylideneen
dc.subjectMetathesisen
dc.subjectPhosphiteen
dc.subjectRutheniumen
dc.subjectRing-closing metathesisen
dc.subjectN-Heterocyclic carbenesen
dc.subjectNobel lectureen
dc.subjectAlkylidene complexesen
dc.subjectPolymerizationen
dc.subjectRompen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleRuthenium indenylidene "1st generation" olefin metathesis catalysts containing triisopropyl phosphiteen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Commissionen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.3762/bjoc.11.166
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.beilstein-journals.org/bjoc/single/downloadSuppInfo.htm?publicId=1860-5397-11-166en
dc.identifier.grantnumberCP-FP 211468-2 EUMETen


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