Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

Citation

Magdysyuk , O V , Adams , F , Liermann , H-P , Spanopoulos , I , Trikalitis , P N , Hirscher , M , Morris , R E , Duncan , M J , McCormick , L J & Dinnebier , R E 2014 , ' Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8 ' , Physical Chemistry Chemical Physics , vol. 16 , no. 43 , pp. 23908-23914 . https://doi.org/10.1039/c4cp03298e

Publication

Physical Chemistry Chemical Physics

Status

Peer reviewed

DOI

https://doi.org/10.1039/c4cp03298e

ISSN

1463-9076

Type

Journal article

Rights

© the Authors 2014. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at http://dx.doi.org/10.1039/C4CP03298E

Collections

University of St Andrews Research

URI

http://hdl.handle.net/10023/7472