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dc.contributor.authorHernandez-Mejia, Carlos
dc.contributor.authorGnanakumar, Edwin S.
dc.contributor.authorOlivos-Suarez, Alma
dc.contributor.authorGascon, Jorge
dc.contributor.authorGreer, Heather Frances
dc.contributor.authorZhou, Wuzong
dc.contributor.authorRothenberg, Gadi
dc.contributor.authorShiju, N. Raveendran
dc.date.accessioned2015-09-15T11:10:03Z
dc.date.available2015-09-15T11:10:03Z
dc.date.issued2016-01-21
dc.identifier.citationHernandez-Mejia , C , Gnanakumar , E S , Olivos-Suarez , A , Gascon , J , Greer , H F , Zhou , W , Rothenberg , G & Shiju , N R 2016 , ' Ru/TiO 2 -catalysed hydrogenation of xylose : the role of crystal structure of the support ' , Catalysis Science & Technology , vol. 6 , no. 2 , pp. 577-582 . https://doi.org/10.1039/C5CY01005Een
dc.identifier.issn2044-4753
dc.identifier.otherPURE: 215925210
dc.identifier.otherPURE UUID: 5f0cc360-005c-4ee2-8153-19b672ac9e4a
dc.identifier.otherScopus: 84955513786
dc.identifier.otherORCID: /0000-0001-9752-7076/work/58055006
dc.identifier.otherWOS: 000368389700030
dc.identifier.urihttp://hdl.handle.net/10023/7464
dc.descriptionC.H.M. acknowledges the National Council of Science and Technology, Mexico (Consejo Nacional de Ciencia y Tecnología CONACyT) for financial support (Scholarship 216968). WZ and HFG thank the EPSRC for a Platform grant (EP/K015540/1).en
dc.description.abstractEffective dispersion of the active species over the support almost always guarantees high catalytic efficiency. To achieve this high dispersion, favourable interaction of the active species with the support is crucial. We show here that the crystal structure of the titania support determines the interaction and consequently the nature of Ru deposited on the support. Similar crystal structures of RuO2 and rutile titania lead to a good lattice matching and ensure a better interaction, maintaining the initial good dispersion of the active species on the support and leading to better activity and selectivity. This highlights the importance of understanding the physico-chemical processes during catalyst preparation steps.
dc.language.isoeng
dc.relation.ispartofCatalysis Science & Technologyen
dc.rightsCopyright 2015 the Authors. This Open Access Article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/).en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleRu/TiO2-catalysed hydrogenation of xylose : the role of crystal structure of the supporten
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C5CY01005E
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/c5/cy/c5cy01005e/c5cy01005e1.pdfen


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