Synthesis and characterisation of Au(I)-(ITent) complexes
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The synthesis of novel [AuCl(ITent)] and [Au(OH)(ITent)] complexes is reported. They have been fully characterised and their steric parameters were assessed by calculating percent buried volumes and producing steric maps from their crystal structures in the solid state.
Patrick , S R , Collado , A , Meiries , S , Slawin , A M Z & Nolan , S P 2015 , ' Synthesis and characterisation of Au(I)-(ITent) complexes ' Journal of Organometallic Chemistry , vol 775 , pp. 152–154 . DOI: 10.1016/j.jorganchem.2014.04.022
Journal of Organometallic Chemistry
Copyright © 2014 Published by Elsevier B.V. NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Organometallic Chemistry. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Organometallic Chemistry, 775, 2015, doi: 10.1016/j.jorganchem.2014.04.022
The ERC (Advanced Investigator Award-FUNCAT), the EPSRC and Syngenta are gratefully acknowledged for support of this work. Umicore AG is acknowledged for their generous gift of auric acid. S.P.N. is a Royal Society Wolfson Research Merit Award holder.