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dc.contributor.authorSowmya, Haliwana B V
dc.contributor.authorSuresha Kumara, Tholappanavara H
dc.contributor.authorGopalpur, Nagendrappa
dc.contributor.authorJasinski, Jerry P
dc.contributor.authorMillikan, Sean P
dc.contributor.authorYathirajan, Hemmige S
dc.contributor.authorGlidewell, Christopher
dc.date.accessioned2015-07-15T15:40:04Z
dc.date.available2015-07-15T15:40:04Z
dc.date.issued2015-06
dc.identifier.citationSowmya , H B V , Suresha Kumara , T H , Gopalpur , N , Jasinski , J P , Millikan , S P , Yathirajan , H S & Glidewell , C 2015 , ' Crystal structures of five (2-chloro-quinolin-3-yl)methyl ethers : supra-molecular assembly in one and two dimensions mediated by hydrogen bonding and π-π stacking ' , Acta Crystallographica Section E: Crystallographic Communications , vol. 71 , no. 6 , pp. 609-17 . https://doi.org/10.1107/S2056989015008233en
dc.identifier.issn2056-9890
dc.identifier.otherPURE: 202736755
dc.identifier.otherPURE UUID: 6446a022-c0f7-488c-8033-20f69544f224
dc.identifier.otherPubMed: 26090133
dc.identifier.otherScopus: 84983150613
dc.identifier.otherWOS: 000369979300061
dc.identifier.urihttp://hdl.handle.net/10023/6996
dc.description.abstractIn the mol­ecules of the title compounds, methyl 5-bromo-2-[(2-chloro­quinolin-3-yl)meth­oxy]benzoate, C18H13BrClNO3, (I), methyl 5-bromo-2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]benzoate, C19H15BrClNO3, (II), methyl 2-[(2-chloro-6-methyl­quinolin-3-yl)meth­oxy]benzoate, C19H16ClNO3, (III), which crystallizes with Z' = 4 in space group P212121, and 2-chloro-3-[(naphthalen-1-yl­oxy)meth­yl]quinoline, C20H14ClNO, (IV), the non-H atoms are nearly coplanar, but in {5-[(2-chloro­quinolin-3-yl)meth­oxy]-4-(hy­droxy­meth­yl)-6-methyl­pyridin-3-yl}methanol, C18H17ClN2O3, (V), the planes of the quinoline unit and of the unfused pyridine ring are almost parallel, although not coplanar. The mol­ecules of (I) are linked by two independent [pi]-[pi] stacking inter­actions to form chains, but there are no hydrogen bonds present in the structure. In (II), the mol­ecules are weakly linked into chains by a single type of [pi]-[pi] stacking inter­action. In (III), three of the four independent mol­ecules are linked by [pi]-[pi] stacking inter­actions but the other mol­ecule does not participate in such inter­actions. Weak C-H...O hydrogen bonds link the mol­ecules into three types of chains, two of which contain just one type of independent mol­ecule while the third type of chain contains two types of mol­ecule. The mol­ecules of (IV) are linked into chains by a C-H...π(arene) hydrogen bond, but [pi]-[pi] stacking inter­actions are absent. In (V), there is an intra­molecular O-H...O hydrogen bond, and mol­ecules are linked into sheets by a combination of O-H...N hydrogen bonds and π-π stacking inter­actions.
dc.format.extent9
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section E: Crystallographic Communicationsen
dc.rightsCopyright 2015 the Authors. Published under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0/uk/legalcode), which permits unrestricted use, provided the original author and source are credited.en
dc.subjectCrystal structureen
dc.subject2-chloro­quinolinesen
dc.subjectMol­ecular conformationen
dc.subjectHydrogen bondingen
dc.subject[pi]-[pi] stacking inter­actionsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleCrystal structures of five (2-chloro-quinolin-3-yl)methyl ethers : supra-molecular assembly in one and two dimensions mediated by hydrogen bonding and π-π stackingen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.1107/S2056989015008233
dc.description.statusPeer revieweden
dc.identifier.urlhttp://scripts.iucr.org/cgi-bin/sendsup?cnor=su5121&type=supplementarymaterialsen


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