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dc.contributor.authorHua, Guoxiong
dc.contributor.authorDu, Junyi
dc.contributor.authorWoollins, J Derek
dc.contributor.authorSurgenor, Brian Andrew
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.date.accessioned2015-07-06T12:10:03Z
dc.date.available2015-07-06T12:10:03Z
dc.date.issued2015-07-03
dc.identifier.citationHua , G , Du , J , Woollins , J D , Surgenor , B A & Slawin , A M Z 2015 , ' Novel fluorinated phosphorus–sulfur heteroatom compounds : synthesis and characterization of ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters ' , Molecules , vol. 20 , no. 7 , pp. 12175-12197 . https://doi.org/10.3390/molecules200712175en
dc.identifier.issn1420-3049
dc.identifier.otherPURE: 199968783
dc.identifier.otherPURE UUID: 575921c1-c2fc-4987-a143-a2701ae041f8
dc.identifier.otherScopus: 84938651971
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56862111
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779176
dc.identifier.otherWOS: 000368695400032
dc.identifier.urihttp://hdl.handle.net/10023/6911
dc.description.abstractA series of novel ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters has been prepared. The reaction of 2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide {[FcP(μ-S)S]2, FcLR} with dry KF or tetrabutylammonium fluoride (TBAF) led to the corresponding potassium and tetrabutylammonium salts of ferrocenyldithiofluorophosphinic acids. Treating potassium ferrocenyldithiofluorophosphinic acid with an equimolar amount of tetraphenylphosphonium chloride readily yielded the corresponding organic adducts, and with mono- and di-halogenated alkanes generated a series of the corresponding esters of ferrocenylphosphonofluoridodithioates. Similarly, using 1,3-epithionaphtho[1,8-cd][1,2,6] oxadiphosphinine 1,3-disulfide or Belleau’s Reagent in place of FcLR resulted in the corresponding novel salts, adducts, and ester derivatives. All new compounds have been characterized by means of multi-NMR (1H, 13C, 31P, 19F) spectroscopy and accurate mass measurement in conjunction with single crystal X-ray crystallography of four structures.
dc.language.isoeng
dc.relation.ispartofMoleculesen
dc.rights© 2015 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).en
dc.subject2,4-diferrocenyl-1,3,2,4-diathiadiphosphetaneen
dc.subject2,4-disulfideen
dc.subjectSalts of phenyldithio- fluorophosphinic acidsen
dc.subjectMono- and di-halogenated alkanesen
dc.subjectEsters of phenylphosphono-fluoridodithioatesen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleNovel fluorinated phosphorus–sulfur heteroatom compounds : synthesis and characterization of ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and estersen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Office of the Principalen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3390/molecules200712175
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.mdpi.com/1420-3049/20/7/12175/s1en


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