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Novel fluorinated phosphorus–sulfur heteroatom compounds : synthesis and characterization of ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Du, Junyi | |
dc.contributor.author | Woollins, J Derek | |
dc.contributor.author | Surgenor, Brian Andrew | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.date.accessioned | 2015-07-06T12:10:03Z | |
dc.date.available | 2015-07-06T12:10:03Z | |
dc.date.issued | 2015-07-03 | |
dc.identifier.citation | Hua , G , Du , J , Woollins , J D , Surgenor , B A & Slawin , A M Z 2015 , ' Novel fluorinated phosphorus–sulfur heteroatom compounds : synthesis and characterization of ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters ' , Molecules , vol. 20 , no. 7 , pp. 12175-12197 . https://doi.org/10.3390/molecules200712175 | en |
dc.identifier.issn | 1420-3049 | |
dc.identifier.other | PURE: 199968783 | |
dc.identifier.other | PURE UUID: 575921c1-c2fc-4987-a143-a2701ae041f8 | |
dc.identifier.other | Scopus: 84938651971 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56862111 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779176 | |
dc.identifier.other | WOS: 000368695400032 | |
dc.identifier.uri | https://hdl.handle.net/10023/6911 | |
dc.description.abstract | A series of novel ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters has been prepared. The reaction of 2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide {[FcP(μ-S)S]2, FcLR} with dry KF or tetrabutylammonium fluoride (TBAF) led to the corresponding potassium and tetrabutylammonium salts of ferrocenyldithiofluorophosphinic acids. Treating potassium ferrocenyldithiofluorophosphinic acid with an equimolar amount of tetraphenylphosphonium chloride readily yielded the corresponding organic adducts, and with mono- and di-halogenated alkanes generated a series of the corresponding esters of ferrocenylphosphonofluoridodithioates. Similarly, using 1,3-epithionaphtho[1,8-cd][1,2,6] oxadiphosphinine 1,3-disulfide or Belleau’s Reagent in place of FcLR resulted in the corresponding novel salts, adducts, and ester derivatives. All new compounds have been characterized by means of multi-NMR (1H, 13C, 31P, 19F) spectroscopy and accurate mass measurement in conjunction with single crystal X-ray crystallography of four structures. | |
dc.language.iso | eng | |
dc.relation.ispartof | Molecules | en |
dc.rights | © 2015 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/). | en |
dc.subject | 2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane | en |
dc.subject | 2,4-disulfide | en |
dc.subject | Salts of phenyldithio- fluorophosphinic acids | en |
dc.subject | Mono- and di-halogenated alkanes | en |
dc.subject | Esters of phenylphosphono-fluoridodithioates | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Novel fluorinated phosphorus–sulfur heteroatom compounds : synthesis and characterization of ferrocenyl- and aryl-phosphonofluorodithioic salts, adducts, and esters | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Office of the Principal | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3390/molecules200712175 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.mdpi.com/1420-3049/20/7/12175/s1 | en |
dc.identifier.grantnumber | EP/K503940/1 | en |
dc.identifier.grantnumber | EP/K031252/1 | en |
dc.identifier.grantnumber | EP/K039210/1 | en |
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