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Platinum bisphosphine complexes of 1,8-naphthosultone
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dc.contributor.author | Diamond, Louise | |
dc.contributor.author | Knight, Fergus Ross | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Fuller, Amy | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.date.accessioned | 2015-06-29T23:10:38Z | |
dc.date.available | 2015-06-29T23:10:38Z | |
dc.date.issued | 2014-10-15 | |
dc.identifier | 138039089 | |
dc.identifier | 4ef9225f-f382-47da-ab93-d424c0fc6564 | |
dc.identifier | 84904562652 | |
dc.identifier | 000343339600046 | |
dc.identifier.citation | Diamond , L , Knight , F R , Cordes , D B , Fuller , A , Slawin , A M Z & Woollins , J D 2014 , ' Platinum bis phosphine complexes of 1,8-naphthosultone ' , Polyhedron , vol. 81 , pp. 356-363 . https://doi.org/10.1016/j.poly.2014.06.042 | en |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/28024023 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56862024 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779192 | |
dc.identifier.uri | https://hdl.handle.net/10023/6873 | |
dc.description | Funding: Engineering and Physical Sciences Research Council (EPSRC) | en |
dc.description.abstract | A series of three platinum (II) bisphosphine complexes 1-3 [Pt(1-(SO2),8-(O)-nap)(PR3)2] (where R3 = Ph3, Ph2Me, Me2Ph) have been prepared by metathesis from cis-[Pt(PR3)2Cl2)] and the dilithium salt of 1,8-naphthosultone. The novel compounds were fully characterised by X-ray crystallography, multinuclear NMR, IR and MS. The molecular structures of 1-3 were compared by measuring the peri-distance, splay angle magnitude, peri-atom displacement, naphthalene ring torsions, aromatic ring orientations and the geometry around the platinum centre. The platinum metal adopts a distorted square planar geometry in all three complexes which causes deformation of the naphthalene system. The degree of molecular deformation does not decrease upon going from 1 to 3 as anticipated, instead a competition between steric effects and intramolecular interactions causes 3 to display distortion intermediate of 1 and 2. | |
dc.format.extent | 8 | |
dc.format.extent | 1232896 | |
dc.language.iso | eng | |
dc.relation.ispartof | Polyhedron | en |
dc.subject | Sulfone | en |
dc.subject | Napthalene | en |
dc.subject | Platinum | en |
dc.subject | Complex | en |
dc.subject | X-Ray structure | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Platinum bisphosphine complexes of 1,8-naphthosultone | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1016/j.poly.2014.06.042 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2015-06-30 |
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