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dc.contributor.authorSengodan, Sivaprakesh
dc.contributor.authorChoi, Siyuk
dc.contributor.authorJun, Areum
dc.contributor.authorShin, Tae Ho
dc.contributor.authorJu, Young-Wan
dc.contributor.authorJeong, Hu Young
dc.contributor.authorShin, Jeeyoung
dc.contributor.authorIrvine, John Thomas Sirr
dc.contributor.authorKim, Guntae
dc.identifier.citationSengodan , S , Choi , S , Jun , A , Shin , T H , Ju , Y-W , Jeong , H Y , Shin , J , Irvine , J T S & Kim , G 2015 , ' Layered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cells ' , Nature Materials , vol. 14 , no. 2 , pp. 205-206 .
dc.identifier.otherPURE: 157935595
dc.identifier.otherPURE UUID: af2bed16-e089-4fa0-af83-782b451dafb6
dc.identifier.otherWOS: 000348600200020
dc.identifier.otherPubMed: 25532072
dc.identifier.otherScopus: 84924258458
dc.identifier.otherORCID: /0000-0002-8394-3359/work/68280683
dc.descriptionThis research was supported by the New & Renewable Energy of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (20113020030060) grant by the Korea government Ministry of Trade, Industry and Energy, the (2013R1A2A2A04015706) through the National Research Foundation of Korea, funded by the Ministry of Science, ICT and Future Planning and the Basic Science Research Program (2013R1A2A2A01007170 and 2010-0021214) through the National Research Foundation of Korea funded by Ministry of Education. We thank The Royal Society for a Wolfson Merit Award (JI) and EPSRC for a research grant (EP/I022570/1).en
dc.description.abstractDifferent layered perovskite-related oxides are known to exhibit important electronic, magnetic and electrochemical properties. Owing to their excellent mixed-ionic and electronic conductivity and fast ​oxygen kinetics, cation layered double perovskite oxides such as PrBaCo2O5 in particular have exhibited excellent properties as solid oxide fuel cell ​oxygen electrodes1. Here, we show for the first time that related layered materials can be used as high-performance fuel electrodes. Good redox stability with tolerance to coking and sulphur contamination from hydrocarbon fuels is demonstrated for the layered perovskite anode PrBaMn2O5+δ (PBMO). The PBMO anode is fabricated by in situ annealing of Pr0.5Ba0.5MnO3−δ in fuel conditions and actual fuel cell operation is demonstrated. At 800 °C, layered PBMO shows high electrical conductivity of 8.16 S cm−1 in 5% ​H2 and demonstrates peak power densities of 1.7 and 1.3 W cm−2 at 850 °C using humidified ​hydrogen and ​propane fuels, respectively.
dc.relation.ispartofNature Materialsen
dc.rightsCopyright authors 2014. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectQD Chemistryen
dc.titleLayered oxygen-deficient double perovskite as an efficient and stable anode for direct hydrocarbon solid oxide fuel cellsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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