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dc.contributor.authorHuang, Xiubing
dc.contributor.authorNi, Chengsheng
dc.contributor.authorZhao, Guixia
dc.contributor.authorIrvine, John T.S.
dc.date.accessioned2015-06-03T11:10:11Z
dc.date.available2015-06-03T11:10:11Z
dc.date.issued2015-06-28
dc.identifier.citationHuang , X , Ni , C , Zhao , G & Irvine , J T S 2015 , ' Oxygen storage capacity and thermal stability of CuMnO 2 -CeO 2 Composite System ' Journal of Materials Chemistry A , vol 3 , no. 24 , pp. 12958-12964 . DOI: 10.1039/C5TA01361Een
dc.identifier.issn2050-7488
dc.identifier.otherPURE: 190852781
dc.identifier.otherPURE UUID: 5526a7a7-1464-4efa-9d99-095c76c3f6da
dc.identifier.otherBibtex: urn:db92db7f6ec12841ceebed3a0601e487
dc.identifier.otherScopus: 84935891963
dc.identifier.urihttp://hdl.handle.net/10023/6741
dc.identifier.urihttp://www.rsc.org/suppdata/c5/ta/c5ta01361e/c5ta01361e1.pdfen
dc.descriptionThe authors gratefully thank the Engineering and Physical Sciences Research Council (EPSRC) platform grant EP/I022570/1 and EP/I022570/2 for financial support.en
dc.description.abstractFast and reversible oxygen diffusion in solid oxides depending on oxygen partial pressure at low temperatures is a promising strategy for improving the overall performance and service lifetime of many energy-related materials. However, the high energy required for the redox reaction of cations and their high thermodynamic barriers have impeded the realization of fast oxygen diffusion at low temperatures. Herein, we report enhanced oxygen diffusion and storage capacity of monoclinic crednerite CuMnO2 at a lower temperature by surface modification with CeO2. The fast and reversible oxygen uptake/release can be attributed to CeO2 that serves as fast oxygen diffusion channel between bulk CuMnO2 and the surrounding atmospheres. Importantly, the amount of CeO2 in the CuMnO2-CeO2 composite system has great effect on the total oxygen storage capacity and redox behaviour. Our findings could provide useful information for developing effective oxygen storage materials in wide energy-related applications.en
dc.language.isoeng
dc.relation.ispartofJournal of Materials Chemistry Aen
dc.rightsCopyright 2015 the Authors. This open access article is licensed under a Creative Commons Attribution 3.0 Unported Licence (http://creativecommons.org/licenses/by/3.0/)en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleOxygen storage capacity and thermal stability of CuMnO2-CeO2 Composite Systemen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttp://dx.doi.org/10.1039/C5TA01361E
dc.description.statusPeer revieweden


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