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Flash vacuum pyrolysis of α-acyl-o-methoxybenzylidenetriphenylphosphoranes to give 2-substituted benzofurans

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Aitken_Flash Vacuum Pyrolysis of alpha-Acyl-o-methoxybenzylidenetriphenylphosphoranes.pdf (149.4Kb)
Date
2000
Author
Aitken, R. Alan
Keywords
ylides
benzofurans
organic chemistry
flash vacuum pyrolysis
FVP
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Abstract
The title stabilised ylides, readily prepared in one step from acid chlorides, are converted upon FVP at 850 °C into 2-substituted benzofurans. When the acyl group is aromatic it appears unchanged as the 2- substituent in the product while for aliphatic examples degradation processes may lead to 2-alkenyl products.
Citation
Aitken, R.A. (2000). Flash Vacuum Pyrolysis of α-Acyl-o-methoxybenzylidenetriphenylphosphoranes to give 2-Substituted Benzofurans. ARKIVOC 1: 798-805
Publication
ARKIVOC
ISSN
14246376
Type
Journal article
Collections
  • Chemistry Research
URI
http://www.arkat-usa.org/get-file/18914/
http://hdl.handle.net/10023/670

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