Chemistry
The School of Chemistry at St Andrews has a long history of research achievement stretching back to 1811. Research activity and strength spans most of the key areas and interfaces in the chemical sciences. Graduates have access to state-of-the-art facilities within Chemistry and in the associated interdisciplinary research centres.
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pH controlled assembly of a self-complementary halogen-bonded dimer
(2016-09-19) - Journal articlePhenols and their corresponding phenoxide anions can form halogen bonds with neutral iodotriazoles. The strength of these interactions depends critically on the protonation state of the oxygen atom – the interaction of the ... -
Rate dependent performance related to crystal structure evolution of Na0.67Mn0.8Mg0.2O2 in a sodium-ion battery
(2015-10-27) - Journal articleSodium-ion batteries are considered as a favorable alternative to the widely used lithium-ion batteries for applications such as grid-scale energy storage. However, to meet the energy density and reliability that is ... -
The crystal structures of two chalcones: (2E)-1-(5-chlorothiophen-2-yl)-3-(2-methylphenyl)prop-2-en-1-one and (2E)-1-(anthracen-9-yl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one
(2016-08-01) - Journal articleIn the crystal of compound (I), C14H11ClOS, molecules are linked by C---H···O hydrogen bonds to form simple it C(5) chains. Compound (II), C26H22O, crystallizes with it Z' = 2 in space group it P-1; one of the molecules ... -
Crystal structure of 2-benzoylamino-it N'-(4-hydroxybenzylidene)-3-(thiophen-2-yl)prop-2-enohydrazide
(2016-08-01) - Journal articleIn the title compound, C21H17N3O3S, the non-H atoms, apart from those in the benzoyl group, are almost coplanar (r.m.s. deviation = 0.049 Å) and the benzoyl group is almost orthogonal to the plane of the rest of the molecule ... -
Crystal structures of two C,N-disubstituted acetamides: 2-(4-chlorophenyl)-N-(2-iodophenyl)acetamide and 2-(4-chlorophenyl)-N-(pyrazin-2-yl)acetamide
(2016-09-01) - Journal articleIn the crystal of 2-(4-chlorophenyl)-N-(2-iodophenyl)acetamide, C14H11ClINO, molecules are linked by a combination of N—H⋯O and C—H⋯O hydrogen bonds to form a C(4)C(4)[R21(7)] chain of rings and chains of this type are ...
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