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Crystal structure of 3-benzoyl-2-[(5-bromo-2-Hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene

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Date
02/2015
Author
Kaur, M.
Jasinski, J.P.
Yathirajan, H.S.
Glidewell, C.
Byrappa, K.
Stoeckli-Evans, H.
Keywords
Crystal structure
2-amino­thio­phene
4,5,6,7-tetra­hydro­benzo[b]thio­phene
Schliff base
Hydrogen bonding
QD Chemistry
DAS
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Abstract
In the cyclo­hexene ring of the title compound, C23H20BrNO3S, the -(CH2)4- atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio­phene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3)°, respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6)°. In the mol­ecule, there is an O-H...N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked via C-H...O hydrogen bonds, forming chains parallel to [100].
Citation
Kaur , M , Jasinski , J P , Yathirajan , H S , Glidewell , C , Byrappa , K & Stoeckli-Evans , H 2015 , ' Crystal structure of 3-benzoyl-2-[(5-bromo-2-Hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene ' , Acta Crystallographica. Section E, Structure reports online , vol. 71 , no. 2 , pp. 176-179 . https://doi.org/10.1107/S2056989015000195
Publication
Acta Crystallographica. Section E, Structure reports online
Status
Peer reviewed
DOI
https://doi.org/10.1107/S2056989015000195
ISSN
1600-5368
Type
Journal article
Rights
Copyright 2015 the Authors. This article is covered by the Creative Commons Attribution license (http://creativecommons.org/licenses/by/2.0/uk/legalcode)
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  • University of St Andrews Research
URL
http://scripts.iucr.org/cgi-bin/sendsup?su5055
URI
http://hdl.handle.net/10023/6686

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