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Palladium(0) NHC complexes : a new avenue to highly efficient phosphorescence

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dc.contributor.authorHenwood, Adam Francis
dc.contributor.authorLesieur, Mathieu
dc.contributor.authorBansal, Ashu Kumar
dc.contributor.authorLemaur, Vincent
dc.contributor.authorBeljonne, David
dc.contributor.authorThompson, David G.
dc.contributor.authorGraham, Duncan
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorSamuel, Ifor David William
dc.contributor.authorCazin, Catherine S.J.
dc.contributor.authorZysman-Colman, Eli
dc.date.accessioned2015-04-29T23:02:02Z
dc.date.available2015-04-29T23:02:02Z
dc.date.issued2015-05-01
dc.identifier178709985
dc.identifier814c2846-b8d9-41f2-a4b8-1d6b221c39d5
dc.identifier84928325241
dc.identifier000353223100072
dc.identifier.citationHenwood , A F , Lesieur , M , Bansal , A K , Lemaur , V , Beljonne , D , Thompson , D G , Graham , D , Slawin , A M Z , Samuel , I D W , Cazin , C S J & Zysman-Colman , E 2015 , ' Palladium(0) NHC complexes : a new avenue to highly efficient phosphorescence ' , Chemical Science , vol. 6 , no. 5 , pp. 3248-3261 . https://doi.org/10.1039/C4SC03914Aen
dc.identifier.issn2041-6520
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639116
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861908
dc.identifier.urihttps://hdl.handle.net/10023/6599
dc.descriptionThe authors are grateful to the Royal Society (University Research Fellowship to CSJC and Wolfson Research Merit Award for IDWS) and to EPSRC (grant: EP1J01771X) for financial support. EZ-C thanks the University of St Andrews for funding.en
dc.description.abstractWe report the first examples of highly luminescent di-coordinated Pd(0) complexes. Five complexes of the form [Pd(L)(L’)] were synthesized, where L = IPr, SIPr or IPr* NHC ligands and L’ = PCy3, or IPr and SIPr NHC ligands. The photophysical properties of these complexes were determined in toluene solution and in solid state and contrasted to the poorly luminescent reference complex [Pd(IPr)(PPh3)]. Organic light-emitting diodes were successfully fabricated but attained external quantum efficiencies of between 0.3 and 0.7%.
dc.format.extent1623157
dc.language.isoeng
dc.relation.ispartofChemical Scienceen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subject.lccQDen
dc.titlePalladium(0) NHC complexes : a new avenue to highly efficient phosphorescenceen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. School of Physics and Astronomyen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Condensed Matter Physicsen
dc.identifier.doi10.1039/C4SC03914A
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/sc/c4/c4sc03914a/c4sc03914a1.pdfen
dc.identifier.urlhttp://www.rsc.org/suppdata/sc/c4/c4sc03914a/c4sc03914a2.cifen
dc.identifier.urlhttp://www.rsc.org/suppdata/sc/c4/c4sc03914a/c4sc03914a3.cifen
dc.identifier.grantnumberEP/J01771X/1en
dc.identifier.grantnumberEP/K039210/1en


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