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dc.contributor.authorShin, Tae Ho
dc.contributor.authorMyung, Jaeha
dc.contributor.authorNaeem, Khan M.
dc.contributor.authorSavaniu, Cristian Daniel
dc.contributor.authorIrvine, John Thomas Sirr
dc.identifier.citationShin , T H , Myung , J , Naeem , K M , Savaniu , C D & Irvine , J T S 2015 , ' Ce(Mn,Fe)O 2 –(La,Sr)(Fe,Mn)O 3 composite as an active cathode for electrochemical reduction of CO 2 in proton conducting solid oxide cells ' , Solid State Ionics , vol. 275 , pp. 106-109 .
dc.identifier.otherPURE: 175276917
dc.identifier.otherPURE UUID: fadde6d9-e790-430e-b008-8fab0aa20ba6
dc.identifier.otherScopus: 84937759861
dc.identifier.otherWOS: 000355372700023
dc.identifier.otherORCID: /0000-0002-8394-3359/work/68280564
dc.descriptionWe thank EPSRC (EP/I022570/1, EP/K015540/1, EP/I038950/1) and the Royal Society (Wolfson Research Merit award) for support.en
dc.description.abstractA solid oxide electrolysis cell concept for reducing CO2 to CO was studied using a proton conducting mixed oxide- BaCe0.7Zr0.1Y0.1Yb0.06Zn0.04O3-δ (BCZYYZ) as an electrolyte. The oxide composite mixture: Ce0.6Mn0.3Fe0.1O2 – La0.6Sr0.4Fe0.9Mn0.1O3 (12.5-87.5 wt%) was examined as enhancing catalyst electrode for CO2 reduction and proton oxidation reaction on the cathode side for avoiding coke formation. Here we demonstrate the successful electrochemical reduction of CO2 in proton conducting SOECs. During electrochemical reduction of CO2 at 700oC, current densities as high as 0.5 A/cm2 and 1 A/cm2 at 1.3 V and 2.2 V respectively, were withdrawn even though the cell employed a 400 μm thick BCZYYZ electrolyte support.
dc.relation.ispartofSolid State Ionicsen
dc.rights© 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (
dc.subjectSolid oxide electrolyseren
dc.subjectComposite cathodeen
dc.subjectCO2 reductionen
dc.subjectProton conductoren
dc.subjectQD Chemistryen
dc.titleCe(Mn,Fe)O2 –(La,Sr)(Fe,Mn)O3 composite as an active cathode for electrochemical reduction of CO2 in proton conducting solid oxide cellsen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.description.statusPeer revieweden

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