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dc.contributor.authorAshbrook, Sharon E.
dc.contributor.authorDawson, Daniel M.
dc.contributor.authorSeymour, Valerie R.
dc.date.accessioned2015-03-20T00:02:00Z
dc.date.available2015-03-20T00:02:00Z
dc.date.issued2014
dc.identifier121316294
dc.identifier692a196c-2dab-4485-b926-0e0868e97211
dc.identifier000334602900006
dc.identifier84898412859
dc.identifier.citationAshbrook , S E , Dawson , D M & Seymour , V R 2014 , ' Recent developments in solid-state NMR spectroscopy of crystalline microporous materials ' , Physical Chemistry Chemical Physics , vol. 16 , no. 18 , pp. 8223-8242 . https://doi.org/10.1039/c4cp00578cen
dc.identifier.issn1463-9076
dc.identifier.otherORCID: /0000-0002-4538-6782/work/56638918
dc.identifier.otherORCID: /0000-0002-8110-4535/work/34029122
dc.identifier.urihttps://hdl.handle.net/10023/6272
dc.description.abstractMicroporous materials, having pores and channels on the same size scale as small to medium molecules, have found many important applications in current technologies, including catalysis, gas separation and drug storage and delivery. Many of their properties and functions are related to their detailed local structure, such as the type and distribution of active sites within the pores, and the specific structures of these active sites. Solid-state NMR spectroscopy has a strong track record of providing the requisite detailed atomic-level insight into the structures of microporous materials, in addition to being able to probe dynamic processes occurring on timescales spanning many orders of magnitude (i.e., from s to ps). In this Perspective, we provide a brief review of some of the basic experimental approaches used in solid-state NMR spectroscopy of microporous materials, and then discuss some more recent advances in this field, particularly those applied to the study of crystalline materials such as zeolites and metal-organic frameworks. These advances include improved software for aiding spectral interpretation, the development of the NMR-crystallography approach to structure determination, new routes for the synthesis of isotopically-labelled materials, methods for the characterisation of host-guest interactions, and methodologies suitable for observing NMR spectra of paramagnetic microporous materials. Finally, we discuss possible future directions, which we believe will have the greatest impact on the field over the coming years.
dc.format.extent20
dc.format.extent2206806
dc.language.isoeng
dc.relation.ispartofPhysical Chemistry Chemical Physicsen
dc.subjectMetal-Organic Frameworksen
dc.subjectNuclear-Magnetic-Resonanceen
dc.subjectAluminophosphate Molecular-Sieveen
dc.subjectAb-Initio Calculationsen
dc.subjectBronsted Acid Sitesen
dc.subjectAngle-Spinning NMRen
dc.subjectMAS-NMRen
dc.subject1st-Principles Calculationsen
dc.subjectIonothermal Synthesisen
dc.subjectQuadrupolar Nucleien
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleRecent developments in solid-state NMR spectroscopy of crystalline microporous materialsen
dc.typeJournal articleen
dc.contributor.sponsorThe Leverhulme Trusten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/c4cp00578c
dc.description.statusPeer revieweden
dc.date.embargoedUntil2015-03-20
dc.identifier.grantnumberF/00 268/BJen


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