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Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores

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Date
19/11/2014
Author
Orofino-Pena, C.
Cortizo-Lacalle, D.
Cameron, J.
Sajjad, M.T.
Manousiadis, P.P.
Findlay, N.J.
Kanibolotsky, A.L.
Amarasinghe, Chiranthika Dimali Amarasinghe
Skabara, P.J.
Tuttle, T.
Turnbull, G.A.
Samuel, D.W.
Keywords
Absorption spectroscopy
BODIPY
Cyclic voltammetry
Photoluminescence
Star-shaped oligofluorene
QD Chemistry
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Abstract
Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1-T-B4 and Y-B1-Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption and photoluminescence spectroscopy of each member of these two families were studied in order to determine their suitability as emissive materials in photonic applications.
Citation
Orofino-Pena , C , Cortizo-Lacalle , D , Cameron , J , Sajjad , M T , Manousiadis , P P , Findlay , N J , Kanibolotsky , A L , Amarasinghe , C D A , Skabara , P J , Tuttle , T , Turnbull , G A & Samuel , D W 2014 , ' Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores ' , Beilstein Journal of Organic Chemistry , vol. 10 , pp. 2704-2714 . https://doi.org/10.3762/bjoc.10.285
Publication
Beilstein Journal of Organic Chemistry
Status
Peer reviewed
DOI
https://doi.org/10.3762/bjoc.10.285
ISSN
1860-5397
Type
Journal article
Rights
© 2014 Orofino-Pena et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Description
The authors wish to thank the EPSRC for funding. PJS thanks the Royal Society for a Wolfson Research Merit Award.
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  • University of St Andrews Research
URL
http://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-10-285#supporting-info
URI
http://hdl.handle.net/10023/6054

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