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Rhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes

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dc.contributor.authorNoonan, Gary M.
dc.contributor.authorCobley, Christopher J.
dc.contributor.authorMahoney, Thomas
dc.contributor.authorClarke, Matthew L.
dc.date.accessioned2015-01-20T15:31:02Z
dc.date.available2015-01-20T15:31:02Z
dc.date.issued2014-02-11
dc.identifier156948836
dc.identifiera98a2d47-6beb-40df-83a0-ae556803e175
dc.identifier000329925900023
dc.identifier84892616755
dc.identifier000329925900023
dc.identifier.citationNoonan , G M , Cobley , C J , Mahoney , T & Clarke , M L 2014 , ' Rhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenes ' , Chemical Communications , vol. 50 , no. 12 , pp. 1475-1477 . https://doi.org/10.1039/c3cc48823cen
dc.identifier.issn1359-7345
dc.identifier.otherORCID: /0000-0002-2444-1244/work/59464613
dc.identifier.urihttps://hdl.handle.net/10023/6032
dc.description.abstractUsing the phospholane-phosphite ligand, BOBPHOS, almost perfect regioselectivities and high enantioselectivities (up to 92% ee) are observed in Rh catalysed enantioselective hydroformylation of vinyl arenes. This can be achieved under solvent-free conditions.
dc.format.extent3
dc.format.extent333925
dc.language.isoeng
dc.relation.ispartofChemical Communicationsen
dc.subjectAsymmetric Hydroformylationen
dc.subjectDiazaphospholane LIGANDSen
dc.subjectHeterocyclic olefinsen
dc.subjectRhodium(I) complexesen
dc.subjectRH(I)-(R,S)-Binaphosen
dc.subjectAldehydesen
dc.subjectAlkenesen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleRhodium/phospholane-phosphite catalysts give unusually high regioselectivity in the enantioselective hydroformylation of vinyl arenesen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/c3cc48823c
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.rsc.org/suppdata/cc/c3/c3cc48823c/c3cc48823c.pdfen
dc.identifier.grantnumberIF120023en


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