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dc.contributor.authorCortizo-Lacalle, Diego
dc.contributor.authorHowells, Calvyn T.
dc.contributor.authorPandey, Upendra K.
dc.contributor.authorCameron, Joseph
dc.contributor.authorFindlay, Neil J.
dc.contributor.authorInigo, Anto Regis
dc.contributor.authorTuttle, Tell
dc.contributor.authorSkabara, Peter J.
dc.contributor.authorSamuel, Ifor D. W.
dc.date.accessioned2015-01-15T15:01:07Z
dc.date.available2015-01-15T15:01:07Z
dc.date.issued2014-11-18
dc.identifier.citationCortizo-Lacalle , D , Howells , C T , Pandey , U K , Cameron , J , Findlay , N J , Inigo , A R , Tuttle , T , Skabara , P J & Samuel , I D W 2014 , ' Solution processable diketopyrrolopyrrole (DPP) cored small molecules with BODIPY end groups as novel donors for organic solar cells ' , Beilstein Journal of Organic Chemistry , vol. 10 , pp. 2683-2695 . https://doi.org/10.3762/bjoc.10.283en
dc.identifier.issn1860-5397
dc.identifier.otherPURE: 161939282
dc.identifier.otherPURE UUID: 17b2605e-4a51-4848-8f9d-5fe688441153
dc.identifier.otherWOS: 000346463100001
dc.identifier.otherScopus: 84920077054
dc.identifier.otherWOS: 000346463100001
dc.identifier.urihttp://hdl.handle.net/10023/6008
dc.descriptionPJS thanks the Royal Society for a Wolfson Research Merit Award.en
dc.description.abstractTwo novel triads based on a diketopyrrolopyrrole (DPP) central core and two 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) units attached by thiophene rings have been synthesised having high molar extinction coefficients. These triads were characterised and used as donor materials in small molecule, solution processable organic solar cells. Both triads were blended with PC71BM as an acceptor in different ratios by wt% and their photovoltaic properties were studied. For both the triads a modest photovoltaic performance was observed, having an efficiency of 0.65%. Moreover, in order to understand the ground and excited state properties and vertical absorption profile of DPP and BODIPY units within the triads, theoretical DFT and TDDFT calculations were performed.
dc.format.extent13
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.rights© 2014 Cortizo-Lacalle et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)en
dc.subjectBODIPYen
dc.subjectDiketopyrrolopyrroleen
dc.subjectOrganic semiconductorsen
dc.subjectOrganic solar cellsen
dc.subjectThiopheneen
dc.subjectElectronic-energy-transferen
dc.subjectField-effect transistorsen
dc.subjectZeta valence qualityen
dc.subjectFilm morphologyen
dc.subjectAcceptor dyadsen
dc.subjectBasi-setsen
dc.subjectPolymeren
dc.subjectDyesen
dc.subjectPerformanceen
dc.subjectDensityen
dc.subjectQC Physicsen
dc.subject.lccQCen
dc.titleSolution processable diketopyrrolopyrrole (DPP) cored small molecules with BODIPY end groups as novel donors for organic solar cellsen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Physics and Astronomyen
dc.contributor.institutionUniversity of St Andrews.Condensed Matter Physicsen
dc.identifier.doihttps://doi.org/10.3762/bjoc.10.283
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.beilstein-journals.org/bjoc/single/articleFullText.htm?publicId=1860-5397-10-283#supporting-infoen


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