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dc.contributor.authorIftekhar, M.
dc.contributor.authorDrewett, N. E.
dc.contributor.authorArmstrong, Robert
dc.contributor.authorHesp, D.
dc.contributor.authorBraga, F.
dc.contributor.authorAhmed, S.
dc.contributor.authorHardwick, L. J.
dc.date.accessioned2015-01-15T13:31:02Z
dc.date.available2015-01-15T13:31:02Z
dc.date.issued2014-10-06
dc.identifier161935909
dc.identifierf968dbbc-2206-46b0-932c-50734cc9251d
dc.identifier000345975500025
dc.identifier84923668502
dc.identifier000345975500025
dc.identifier.citationIftekhar , M , Drewett , N E , Armstrong , R , Hesp , D , Braga , F , Ahmed , S & Hardwick , L J 2014 , ' Characterization of aluminum doped lithium-manganese rich composites for higher rate lithium-ion cathodes ' , Journal of The Electrochemical Society , vol. 161 , no. 14 , pp. A2109-A2116 . https://doi.org/10.1149/2.0441414jesen
dc.identifier.issn0013-4651
dc.identifier.otherORCID: /0000-0003-1937-0936/work/28123634
dc.identifier.urihttps://hdl.handle.net/10023/6007
dc.descriptionThe authors acknowledge the support from the International Research Support Initiative Program, Higher Education Commission, Pakistan; the Science without Borders Program, Ministério da Educação, Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Brazil; and the Engineering and Physical Sciences Research Council (EPRSC) under grant EP/K016954/1en
dc.description.abstractThe effect of synthesis method and aluminum doping on layered lithium-manganese rich, mixed metal oxides is presented. Co-precipitation and sol-gel synthesized lithium-manganese rich composite materials revealed differences in capacity and cycle life, which appears from X-ray photoelectron spectra to be strongly related to the particles' surface reactivity. Small amounts of aluminum doping to the sol-gel material were shown to improve the rate capability and cyclability, in addition to decreasing voltage fade, as shown by differential capacity plots. The electrochemistry of an aluminum doped material was revealed to be highly dependent on the degree of aluminum doping - with the behavior of 1% doped material giving a maximum capacity of 201 mAh g-1 at 150 mAg-1 and a capacity retention of 88% after 200 cycles.
dc.format.extent8
dc.format.extent1423062
dc.language.isoeng
dc.relation.ispartofJournal of The Electrochemical Societyen
dc.subjectElectrochemical performanceen
dc.subjectSecondary batteriesen
dc.subjectElectrodes Men
dc.subjectLIen
dc.subjectMNen
dc.subjectNIen
dc.subjectCOen
dc.subjectCapacityen
dc.subjectOxygenen
dc.subjectSubstitutionen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleCharacterization of aluminum doped lithium-manganese rich composites for higher rate lithium-ion cathodesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doi10.1149/2.0441414jes
dc.description.statusPeer revieweden


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