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Synthesis of tsetse fly attractants from a cashew nut shell extract by isomerising metathesis
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dc.contributor.author | Baader, S. | |
dc.contributor.author | Podsiadly, P. E. | |
dc.contributor.author | Cole-Hamilton, D. J. | |
dc.contributor.author | Goossen, L. J. | |
dc.date.accessioned | 2015-01-05T12:31:02Z | |
dc.date.available | 2015-01-05T12:31:02Z | |
dc.date.issued | 2014-12-01 | |
dc.identifier | 161192795 | |
dc.identifier | e1f05d03-e9cc-4ac0-b155-7955188b27f3 | |
dc.identifier | 000345455100007 | |
dc.identifier | 84911895399 | |
dc.identifier | 000345455100007 | |
dc.identifier.citation | Baader , S , Podsiadly , P E , Cole-Hamilton , D J & Goossen , L J 2014 , ' Synthesis of tsetse fly attractants from a cashew nut shell extract by isomerising metathesis ' , Green Chemistry , vol. 16 , no. 12 , pp. 4885-4890 . https://doi.org/10.1039/c4gc01269k | en |
dc.identifier.issn | 1463-9262 | |
dc.identifier.uri | https://hdl.handle.net/10023/5965 | |
dc.description | The authors thank NanoKat, the Collaborative Research Centre SFB/TRR 88 “3MET”, Carl Zeiss (RCR) and the Deutsche Bundesstiftung Umwelt (fellowship to S.B.) for financial support. | en |
dc.description.abstract | Starting from a purified cashew nut shell extract containing mostly anacardic acid derivatives, the tsetse fly attractants 3-ethyl- and 3-propylphenol were selectively synthesised. The mixture was first converted into 3-(non-8-enyl)phenol in 98% purity via ethenolysis and distillation with concomitant decarboxylation. The olefinic side chain was then shortened by isomerising cross-metathesis with short-chain olefins in the presence of a [Pd(μ-Br)(tBu3P)]2 isomerisation catalyst and a second-generation Hoveyda–Grubbs catalyst, and the synthesis was completed by a hydrogenation step. | |
dc.format.extent | 6 | |
dc.format.extent | 418684 | |
dc.language.iso | eng | |
dc.relation.ispartof | Green Chemistry | en |
dc.subject | Olefin metathesis | en |
dc.subject | Carboxylic-acids | en |
dc.subject | Sleeping sickness | en |
dc.subject | Methyl oleate | en |
dc.subject | Buffalo urine | en |
dc.subject | Ethenolysis | en |
dc.subject | Catalysts | en |
dc.subject | Cardanol | en |
dc.subject | Liquid | en |
dc.subject | Chemicals | en |
dc.subject | QD Chemistry | en |
dc.subject | SDG 3 - Good Health and Well-being | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis of tsetse fly attractants from a cashew nut shell extract by isomerising metathesis | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/c4gc01269k | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.rsc.org/suppdata/gc/c4/c4gc01269k/c4gc01269k1.pdf | en |
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