Exploring energy transfer in luminescent heterometallic ruthenium–iridium ion pairs
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Here, we report the synthesis of a luminescent ion pair with the formula [Ru(dtBubpy)3][Ir(ppy)2(CN)2]2. The crystal structure of this three component, heterometallic assembly is described, along with the luminescence properties of the salt. The modulation of the energy transfer between the blue-emitting iridium complex and the red-emitting ruthenium complex is also discussed as a function of both medium and concentration.
Sandroni , M & Zysman-Colman , E 2014 , ' Exploring energy transfer in luminescent heterometallic ruthenium–iridium ion pairs ' Dalton Transactions , vol. 43 , no. 9 , pp. 3676-3680 . https://doi.org/10.1039/C3DT53170H
© Royal Society of Chemistry 2014. This is the author's version of this work, published in Dalton Transactions 43(9), available from DOI: 10.1039/C3DT53170H
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