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Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
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dc.contributor.author | Adamkiewicz, Malgorzata | |
dc.contributor.author | O'Hagan, David | |
dc.contributor.author | Hähner, Georg | |
dc.date.accessioned | 2014-12-17T22:31:04Z | |
dc.date.available | 2014-12-17T22:31:04Z | |
dc.date.issued | 2014-12-05 | |
dc.identifier | 159443387 | |
dc.identifier | 31435929-4561-41be-9eaa-cf8362e4ea54 | |
dc.identifier | 000346467600002 | |
dc.identifier | 84920067704 | |
dc.identifier.citation | Adamkiewicz , M , O'Hagan , D & Hähner , G 2014 , ' Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) ' , Beilstein Journal of Organic Chemistry , vol. 10 , pp. 2897–2902 . https://doi.org/10.3762/bjoc.10.307 | en |
dc.identifier.issn | 1860-5397 | |
dc.identifier.other | ORCID: /0000-0002-6765-344X/work/60426691 | |
dc.identifier.other | ORCID: /0000-0002-0510-5552/work/68281236 | |
dc.identifier.uri | https://hdl.handle.net/10023/5934 | |
dc.description | We thank the Scottish Funding Council for a SPIRIT Studentship (MA) and DO'H thanks the ERC for an Advanced Investigator Grant. Some of the X-ray photoelectron spectra were obtained at the National EPSRC XPS User ’s Service (NEXUS) at Newcastle University, UK. | en |
dc.description.abstract | C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage. | |
dc.format.extent | 6 | |
dc.format.extent | 2376348 | |
dc.language.iso | eng | |
dc.relation.ispartof | Beilstein Journal of Organic Chemistry | en |
dc.subject | difluoro- | en |
dc.subject | dichloro- | en |
dc.subject | dibromomethylenecyclopropanes | en |
dc.subject | dihalocarbenes | en |
dc.subject | Self-assembled monolayers | en |
dc.subject | surface coating | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.3762/bjoc.10.307 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/H022651/1 | en |
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