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Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

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dc.contributor.authorAdamkiewicz, Malgorzata
dc.contributor.authorO'Hagan, David
dc.contributor.authorHähner, Georg
dc.date.accessioned2014-12-17T22:31:04Z
dc.date.available2014-12-17T22:31:04Z
dc.date.issued2014-12-05
dc.identifier159443387
dc.identifier31435929-4561-41be-9eaa-cf8362e4ea54
dc.identifier000346467600002
dc.identifier84920067704
dc.identifier.citationAdamkiewicz , M , O'Hagan , D & Hähner , G 2014 , ' Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) ' , Beilstein Journal of Organic Chemistry , vol. 10 , pp. 2897–2902 . https://doi.org/10.3762/bjoc.10.307en
dc.identifier.issn1860-5397
dc.identifier.otherORCID: /0000-0002-6765-344X/work/60426691
dc.identifier.otherORCID: /0000-0002-0510-5552/work/68281236
dc.identifier.urihttps://hdl.handle.net/10023/5934
dc.descriptionWe thank the Scottish Funding Council for a SPIRIT Studentship (MA) and DO'H thanks the ERC for an Advanced Investigator Grant. Some of the X-ray photoelectron spectra were obtained at the National EPSRC XPS User ’s Service (NEXUS) at Newcastle University, UK.en
dc.description.abstractC11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.
dc.format.extent6
dc.format.extent2376348
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.subjectdifluoro-en
dc.subjectdichloro-en
dc.subjectdibromomethylenecyclopropanesen
dc.subjectdihalocarbenesen
dc.subjectSelf-assembled monolayersen
dc.subjectsurface coatingen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleOrganic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)en
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3762/bjoc.10.307
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/H022651/1en


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