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Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

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dc.contributor.authorAdamkiewicz, Malgorzata
dc.contributor.authorO'Hagan, David
dc.contributor.authorHähner, Georg
dc.date.accessioned2014-12-17T22:31:04Z
dc.date.available2014-12-17T22:31:04Z
dc.date.issued2014-12-05
dc.identifier.citationAdamkiewicz , M , O'Hagan , D & Hähner , G 2014 , ' Organic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) ' , Beilstein Journal of Organic Chemistry , vol. 10 , pp. 2897–2902 . https://doi.org/10.3762/bjoc.10.307en
dc.identifier.issn1860-5397
dc.identifier.otherPURE: 159443387
dc.identifier.otherPURE UUID: 31435929-4561-41be-9eaa-cf8362e4ea54
dc.identifier.otherWOS: 000346467600002
dc.identifier.otherScopus: 84920067704
dc.identifier.otherORCID: /0000-0002-6765-344X/work/60426691
dc.identifier.otherORCID: /0000-0002-0510-5552/work/68281236
dc.identifier.urihttps://hdl.handle.net/10023/5934
dc.descriptionWe thank the Scottish Funding Council for a SPIRIT Studentship (MA) and DO'H thanks the ERC for an Advanced Investigator Grant. Some of the X-ray photoelectron spectra were obtained at the National EPSRC XPS User ’s Service (NEXUS) at Newcastle University, UK.en
dc.description.abstractC11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofBeilstein Journal of Organic Chemistryen
dc.rights© 2014 Adamkiewicz et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)en
dc.subjectdifluoro-en
dc.subjectdichloro-en
dc.subjectdibromomethylenecyclopropanesen
dc.subjectdihalocarbenesen
dc.subjectSelf-assembled monolayersen
dc.subjectsurface coatingen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleOrganic chemistry on surfaces : direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)en
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3762/bjoc.10.307
dc.description.statusPeer revieweden
dc.identifier.grantnumberEP/H022651/1en


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