Thermodynamic properties, electron spin resonance and underlying spin model in Cu3Y(SeO3)2O2Cl
Abstract
We report a detailed study of the magnetic properties of the buckled kagome compound Cu3Y(SeO3)2O2Cl using heat capacity, magnetization, powder neutron diffraction, electron spin resonance and first-principles calculations. The crystal structure is confirmed to be isotypic with the mineral francisite, with orthorhombic space group symmetry Pmmn throughout the temperature range 5 – 300 K. Magnetization, heat capacity and neutron diffraction confirm long range magnetic order below TN = 35 K. The electron spin resonance spectra reveal the presence of two modes corresponding to two different crystallographic Cu positions. The principal g-values of the g-tensor of Cu(1) sites were found to be g1 = 2.18(4), g2 = 2.10(6) and g3 = 2.05(9), while the effective g-factor of Cu(2) sites is almost isotropic and is on average g = 2.09(5). At low temperatures, Cu3Y(SeO3)2O2Cl undergoes a metamagnetic transition, with a critical field BC = 2.6 T at 2 K, due to the suppression of the inter-plane exchange interactions and saturates in modest magnetic field, BS ≤8 T. The first-principles calculations allow an estimation of both intra-plane and inter-plane exchange interactions. The weakness of the inter-plane exchange interaction results in low values of the critical fields for the metamagnetic transition, while the competition between intra-plane exchange interactions of different signs results in a similarly low value of the saturation field.
Citation
Zakharov , K V , Zvereva , E A , Berdonosov , P S , Kuznetsova , E S , Dolgikh , V A , Clark , L M , Black , C , Lightfoot , P , Kockelmann , W , Pchelkina , Z V , Streltsov , S V , Volkova , O S & Vasiliev , A N 2014 , ' Thermodynamic properties, electron spin resonance and underlying spin model in Cu 3 Y(SeO 3 ) 2 O 2 Cl ' , Physical Review. B, Condensed matter and materials physics , vol. 90 , 214417 . https://doi.org/10.1103/PhysRevB.90.214417
Publication
Physical Review. B, Condensed matter and materials physics
Status
Peer reviewed
ISSN
1098-0121Type
Journal article
Description
The collaboration between the University of St Andrews and Moscow State University was funded by a Royal Society International Exchanges grant, in collaboration with the RFBR (12-03-92604). P.L. and L.C. also thank the Leverhulme Trust (Award RPG-2013-343).Collections
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