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A new synthetic route to p-methoxy-2,6-disubstituted anilines and their conversion into N-heterocyclic carbene precursors

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Nolan_2014_Synlett_ANew.pdf (227.3Kb)
Date
2014
Author
Meiries, Sebastien Michel Bernard
Nolan, Steven Patrick
Funder
The Royal Society
European Research Council
European Commission
Grant ID
WM100010
FP7-227817 FUNCAT
246461
Keywords
Ligands
Nucleophilic aromatic
Copper
Catalysis
Carbenes
QD Chemistry
Metadata
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Abstract
The development of new N-heterocyclic carbenes (NHC) is a key feature in this now mainstream research area to access novel chemical properties and reactivity that are essential for the discovery of original applications. Up to now, only a few reliable methods have proven suitable for the preparation of methoxylated anilines to ultimately access methoxylated NHC. We are pleased to report here a straightforward and scalable approach to address this matter.
Citation
Meiries , S M B & Nolan , S P 2014 , ' A new synthetic route to p -methoxy-2,6-disubstituted anilines and their conversion into N-heterocyclic carbene precursors ' , Synlett , vol. 25 , no. 3 , pp. 393-398 . https://doi.org/10.1055/s-0033-1340105
Publication
Synlett
Status
Peer reviewed
DOI
https://doi.org/10.1055/s-0033-1340105
ISSN
0936-5214
Type
Journal item
Rights
© Georg Thieme Verlag Stuttgart · New York
Collections
  • University of St Andrews Research
URI
http://hdl.handle.net/10023/5858

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.

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